(η5-C6Me5)(CO)2FeP(Cr(CO)5)PC6H3(CF3)2-(2,6)

Base Information

• Chemical Name: (η5-C6Me5)(CO)2FeP(Cr(CO)5)PC6H3(CF3)2-(2,6)
• CAS No.: 126504-07-2
• Molecular Formula: C₂₅H₁₈CrF₆FeO₇P₂
• Molecular Weight: 714.195
• Mol file: 126504-07-2.mol

Synonyms:

Chemical Property of (η5-C6Me5)(CO)2FeP(Cr(CO)5)PC6H3(CF3)2-(2,6)

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of (η5-C6Me5)(CO)2FeP(Cr(CO)5)PC6H3(CF3)2-(2,6)

There total 1 articles about (η5-C6Me5)(CO)2FeP(Cr(CO)5)PC6H3(CF3)2-(2,6) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 7.0%

pentacarbonyl(η2-cis-cyclooctene)chromium(0) (92937-36-5,92889-73-1) + (η5-C5Me5)(CO)2FeP(SiMe3)2 + <2,6-bis(trifluoromethyl)phenyl>dichlorophosphine (115044-02-5) → (η5-C6Me5)(CO)2FeP(Cr(CO)5)PC6H3(CF3)2-(2,6) (126504-07-2) + (2,6-(CF3)2C6H3P)2Cr(CO)5 (126504-08-3)

Guidance literature:

In tetrahydrofuran; byproducts: Me2SiCl, C8H14; under argon, 2,6-(CF3)2C6H3PCl2 added to soln. of (η5-C5Me5)(CO)2FeP(SiMe3)2 in THF at -78 ° C, stirring for 1 h, warming up to 0 ° C, addition of (Z-C8H14)Cr(CO)5, warming up to room temp., stirring for 12 h; evapn., chromy. (florisil, petroleum ether/ether), first red band Fe-Cr complex, dark red solid obtained, elem. anal., second red brown band Cr complex, red brown solid obtained, elem. anal.;

upstream raw materials:

pentacarbonyl(η2-cis-cyclooctene)chromium(0)

<2,6-bis(trifluoromethyl)phenyl>dichlorophosphine