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Technology Process of (E)-1-(Anthracen-9-yl)-N-(naphthalen-2-yl)methanimine

(E)-1-(Anthracen-9-yl)-N-(naphthalen-2-yl)methanimine

Base Information
  • Chemical Name:(E)-1-(Anthracen-9-yl)-N-(naphthalen-2-yl)methanimine
  • CAS No.:18304-49-9
  • Molecular Formula:C25H17N
  • Molecular Weight:331.417
  • Hs Code.:
  • DSSTox Substance ID:DTXSID60542239
  • Mol file:18304-49-9.mol
(E)-1-(Anthracen-9-yl)-N-(naphthalen-2-yl)methanimine

Synonyms:18304-49-9;(E)-1-(Anthracen-9-yl)-N-(naphthalen-2-yl)methanimine;DTXSID60542239;9-[N-(2-naphthyl)formimidoyl]anthracene

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Chemical Property of (E)-1-(Anthracen-9-yl)-N-(naphthalen-2-yl)methanimine
Chemical Property:
  • Melting Point:>225 °C 
  • Boiling Point:570.0±19.0 °C(Predicted) 
  • PSA：12.36000 
  • Density:1.11±0.1 g/cm3(Predicted) 
  • LogP:6.89680 
  • XLogP3:7
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:1
  • Rotatable Bond Count:2
  • Exact Mass:331.136099547
  • Heavy Atom Count:26
  • Complexity:474
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MSDS Files:

SDS file from LookChem

Useful:
  • Canonical SMILES:C1=CC=C2C=C(C=CC2=C1)N=CC3=C4C=CC=CC4=CC5=CC=CC=C53
Refernces

ANTHRACENE DERIVATIVES OF BENZOQUINOLINE. SYNTHESIS, SPECTRA, AND LUMINESCENCE

10.1007/BF00515228

The research focuses on the synthesis, spectral, and luminescence properties of anthracene derivatives of benzo[f]quinoline. The key chemicals involved in the research include 9-[N-(2-naphthyl)formimidoyl]anthracene, various methyl ketones such as acetophenone and substituted acetophenones, and other reagents like concentrated HCl, butanol, nitrobenzene, and 2-naphthylamine hydrochloride. The synthesis process involves condensation reactions under acid catalysis, leading to the formation of l-R-3-(9-anthryl)benzo[f]quinolines and byproducts like l-R-3-(9-anthyl)-2-propen-l-ones and N-[l-(p-aminophenyl)-3-(9-anthryl)-2-propen-l-ylidene]-2-naphthylamines. The spectral properties of these compounds were examined using IR, UV, and mass spectrometry, while their luminescence characteristics were assessed through fluorescence spectra and quantum yield measurements. The study highlights the significant contribution of the anthracene ring to the light absorption capabilities of these molecules and investigates the influence of different substituents on their luminescence behavior.

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