C₅H₅FeCO(P(C₆H₅)3)CHCHCN

Base Information

• Chemical Name: C₅H₅FeCO(P(C₆H₅)3)CHCHCN
• CAS No.: 114681-02-6
• Molecular Formula: C₂₇H₂₂FeNOP
• Molecular Weight: 463.299
• Mol file: 114681-02-6.mol

Synonyms:

Chemical Property of C₅H₅FeCO(P(C₆H₅)3)CHCHCN

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of C₅H₅FeCO(P(C₆H₅)3)CHCHCN

There total 1 articles about C₅H₅FeCO(P(C₆H₅)3)CHCHCN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(cyclopentadienyl)(CO)(PPh3)FeH + propiolonitrile (1070-71-9) → C5H5FeCO(P(C6H5)3)CHCHCN (114681-02-6) + C5H5FeCO(P(C6H5)3)CCNCH2 (114657-25-9)

Guidance literature:

In toluene; the iron complex in toluene is frozen in liquid nitrogen and the alkyneis condensed into the reaction tube (using Schlenk technique), the mixt. is stirred at room temp. for 6 to 40 h; the soln. is evaporated, the residue is dissolved in CH2Cl2 and chromd.on Florisil, elution with CH2Cl2/THF, chromy. on alumina gave a mixt. of two isomers, identified by spectroscopy;

DOI:10.1016/S0022-328X(00)99754-7

upstream raw materials:

propiolonitrile