Oxirane, 2-methyl-2-[(1R)-4-methyl-3-cyclohexen-1-yl]-

Base Information

Chemical Name:Oxirane, 2-methyl-2-[(1R)-4-methyl-3-cyclohexen-1-yl]-
CAS No.:184488-93-5
Molecular Formula:C10H16O
Molecular Weight:152.236
Hs Code.:
DSSTox Substance ID:DTXSID80449978
Nikkaji Number:J185.801G
Mol file:184488-93-5.mol

Synonyms:184488-93-5;Oxirane, 2-methyl-2-[(1R)-4-methyl-3-cyclohexen-1-yl]-;(+)-Limonene 8,9-epoxide;SCHEMBL5066784;DTXSID80449978;(4R,8Rs)-limonene-8,9-epoxide;AKOS006303373

Suppliers and Price of Oxirane, 2-methyl-2-[(1R)-4-methyl-3-cyclohexen-1-yl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Oxirane, 2-methyl-2-[(1R)-4-methyl-3-cyclohexen-1-yl]-

Chemical Property:

XLogP3:1.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:152.120115130
Heavy Atom Count:11
Complexity:195

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CCC(CC1)C2(CO2)C
Isomeric SMILES:CC1=CC[C@@H](CC1)C2(CO2)C

Technology Process of Oxirane, 2-methyl-2-[(1R)-4-methyl-3-cyclohexen-1-yl]-

There total 14 articles about Oxirane, 2-methyl-2-[(1R)-4-methyl-3-cyclohexen-1-yl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 5989-27-5,555-08-8,8022-90-0,9003-73-0,95327-98-3
D-limonene

: 184488-93-5
(R)-8,9-limonene oxide

: 203719-54-4
(1RS,2SR,4R)-limonene-1,2-epoxide

Guidance literature:: With 1H-imidazole; dihydrogen peroxide; sodium N-dodecanoyl-L-proplinate; Mn[5-(4-C₆H₄CO-(N-L-proline))-10,15,20-Ph₃-porphyrinyl]Cl; In ethanol; water; at 25 ℃; for 0.166667h; Further Variations:; Catalysts; Reagents; Product distribution;
DOI:10.1016/j.tetasy.2004.05.020

Reference yield: 85.0%

: 5989-27-5,555-08-8,8022-90-0,9003-73-0,95327-98-3
D-limonene

: 184488-93-5
(R)-8,9-limonene oxide

Guidance literature:: With perchloric acid; dihydrogen peroxide; In water; acetonitrile; tert-butyl alcohol; at 60 ℃; for 0.166667h; stereoselective reaction;
DOI:10.1016/j.cattod.2011.07.007

Reference yield: 83.0%

: 5989-27-5,555-08-8,8022-90-0,9003-73-0,95327-98-3
D-limonene

: 1195-92-2
(4R)-limonene 1,2-epoxide

: 184488-93-5
(R)-8,9-limonene oxide

Guidance literature:: With tert.-butylhydroperoxide; [Mo₂(O)₄{[2,2'-(1,3-phenylene)bis(4,5-dihydrooxazole-4,2-diyl)]dimethanol}(acac)₂]; In 1,2-dichloro-ethane; for 6h; regioselective reaction; Reflux;
DOI:10.1016/j.poly.2014.01.004