(2E)-2-[(3,4-dichlorophenyl)imino]-1-phenylethanone

Base Information

• Chemical Name: (2E)-2-[(3,4-dichlorophenyl)imino]-1-phenylethanone
• CAS No.: 79807-20-8
• Molecular Formula: C14H9Cl2NO
• Molecular Weight: 278.1334
• Mol file: 79807-20-8.mol

Synonyms:

Chemical Property of (2E)-2-[(3,4-dichlorophenyl)imino]-1-phenylethanone

Chemical Property:

• Vapor Pressure: 1.88E-07mmHg at 25°C
• Boiling Point: 425.7°C at 760 mmHg
• Flash Point: 167.7°C
• Density: 1.25g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (2E)-2-[(3,4-dichlorophenyl)imino]-1-phenylethanone

There total 2 articles about (2E)-2-[(3,4-dichlorophenyl)imino]-1-phenylethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

3,4-dichloro-N-(α-methoxyphenacyl)aniline (79807-21-9) → 3,4-dichloro-N-phenacylideneaniline (79807-20-8)

Guidance literature:

palladium on activated charcoal; In benzene; for 20h; Heating; further catalysts;

DOI:10.1039/P19810002435

Reference yield:

phenylglyoxal hydrate (1074-12-0) → 3,4-dichloro-N-phenacylideneaniline (79807-20-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 69 percent / 16 h / Heating

2: 73 percent / 10percent palladium-on-charcoal / benzene / 20 h / Heating; further catalysts

palladium on activated charcoal; In benzene;

DOI:10.1039/P19810002435

Reference yield: 88.0%

3,4-dichloro-N-phenacylideneaniline (79807-20-8) → 2-(3,4-dichloroanilino)-1-phenylethanol (79807-41-3)

Guidance literature:

With sodium tetrahydroborate; In tetrahydrofuran; at 25 ℃; for 2h;

DOI:10.1039/P19810002443

upstream raw materials:

3,4-dichloro-N-(α-methoxyphenacyl)aniline

phenylglyoxal hydrate

Downstream raw materials:

3,4-dichloro-N-(α-acetamidophenacyl)aniline

3,4-dichloro-N-(α-methoxyphenacyl)aniline

diethyl α-<(3,4-dichloroanilino)phenacyl>malonate

[2-(3,4-Dichloro-phenyl)-2-aza-bicyclo[2.2.1]hept-5-en-3-yl]-phenyl-methanone

Refernces