Technology Process of 1H-Phosphindole, 3-butyl-1,2-diphenyl-, 1-oxide
There total 6 articles about 1H-Phosphindole, 3-butyl-1,2-diphenyl-, 1-oxide which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C28H34NP;
With
trifluorormethanesulfonic acid;
In
chlorobenzene;
at 20 ℃;
for 12h;
Sealed tube;
Inert atmosphere;
With
dihydrogen peroxide;
In
water; chlorobenzene;
for 0.25h;
Sealed tube;
Inert atmosphere;
DOI:10.1021/acs.orglett.6b02868
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: triethylamine / diethyl ether / 3 h / 0 - 20 °C / Inert atmosphere
1.2: 3 h / 20 °C / Inert atmosphere
2.1: tris(acetonitrile)(η5-pentamethylcyclopentadienyl)rhodium(III) hexafluoroantimonate; acetic acid / chlorobenzene / 12 h / 120 °C / Sealed tube; Inert atmosphere
3.1: methyl trifluoromethanesulfonate / chlorobenzene / 6 h / 20 °C / Sealed tube; Inert atmosphere
3.2: 1 h / 20 °C / Sealed tube; Inert atmosphere
4.1: trifluorormethanesulfonic acid / chlorobenzene / 12 h / 20 °C / Sealed tube; Inert atmosphere
4.2: 0.25 h / Sealed tube; Inert atmosphere
With
tris(acetonitrile)(η5-pentamethylcyclopentadienyl)rhodium(III) hexafluoroantimonate; trifluorormethanesulfonic acid; acetic acid; triethylamine; methyl trifluoromethanesulfonate;
In
diethyl ether; chlorobenzene;
DOI:10.1021/acs.orglett.6b02868
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: methyl trifluoromethanesulfonate / chlorobenzene / 6 h / 20 °C / Sealed tube; Inert atmosphere
1.2: 1 h / 20 °C / Sealed tube; Inert atmosphere
2.1: trifluorormethanesulfonic acid / chlorobenzene / 12 h / 20 °C / Sealed tube; Inert atmosphere
2.2: 0.25 h / Sealed tube; Inert atmosphere
With
trifluorormethanesulfonic acid; methyl trifluoromethanesulfonate;
In
chlorobenzene;
DOI:10.1021/acs.orglett.6b02868
