1,1':3',1''-Terphenyl, 4,4''-bis(bromomethyl)-

Base Information

Chemical Name:1,1':3',1''-Terphenyl, 4,4''-bis(bromomethyl)-
CAS No.:19399-69-0
Molecular Formula:C20H16Br2
Molecular Weight:416.155
Hs Code.:
Mol file:19399-69-0.mol

Synonyms:4,4''-bis(bromomethyl)-1,1':3',1''-terphenyl;4,4'-bis(bromomethyl)-1,1':3',1''-terphenyl;4,4''-bis(bromomethyl)-1.1:3',1'-terphenyl;4,4''-Bis-bromomethyl-[1,1';3',1'']terphenyl;4,4''-Bis-brommethyl-m-terphenyl;

Suppliers and Price of 1,1':3',1''-Terphenyl, 4,4''-bis(bromomethyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
4,4''-BIS-BROMOMETHYL-(1,1':3',1'')TERPHENYL AldrichCPR
100MG
$ 144.00

Sigma-Aldrich
4,4''-BIS-BROMOMETHYL-(1,1',3',1'')TERPHENYL AldrichCPR
100MG
$ 144.00

Total 2 raw suppliers

Chemical Property of 1,1':3',1''-Terphenyl, 4,4''-bis(bromomethyl)-

Chemical Property:

Melting Point:108 °C
PSA：0.00000
LogP:6.81040

Purity/Quality:

98%,99%, ^*data from raw suppliers

4,4''-BIS-BROMOMETHYL-(1,1':3',1'')TERPHENYL AldrichCPR ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,1':3',1''-Terphenyl, 4,4''-bis(bromomethyl)-

There total 8 articles about 1,1':3',1''-Terphenyl, 4,4''-bis(bromomethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 158228-77-4
4,4''-bis(hydroxymethyl)-1,1':3',1''-terphenyl

: 19399-69-0
1,3-bis[4-(bromomethyl)phenyl]benzene

Guidance literature:: With hydrogen bromide; cetyltributylphosphonium bromide; at 105 ℃; for 12h;
DOI:10.1016/S0040-4020(01)85369-2

Reference yield: 83.0%

: 19399-68-9
1,3-di(p-tolyl)benzene

: 19399-69-0
1,3-bis[4-(bromomethyl)phenyl]benzene

Guidance literature:: With N-Bromosuccinimide; Perbenzoic acid; In tetrachloromethane; for 40h; Heating;
DOI:10.1016/0040-4020(94)01016-S

Reference yield:

: 4294-57-9
para-methylphenylmagnesium bromide

: 19399-69-0
1,3-bis[4-(bromomethyl)phenyl]benzene

Guidance literature:: Multi-step reaction with 2 steps

1: 2.) 6N HCl / 1.) THF, reflux, 3 h

2: 83 percent / NBS, benzoyl peroxide / CCl₄ / 40 h / Heating

With hydrogenchloride; N-Bromosuccinimide; Perbenzoic acid; In tetrachloromethane;
DOI:10.1016/0040-4020(94)01016-S