Bicyclo[7.2.0]undecan-5-ol, 10,10-dimethyl-2,6-bis(methylene)-, (1S,5R,9R)-

Base Information

Chemical Name:Bicyclo[7.2.0]undecan-5-ol, 10,10-dimethyl-2,6-bis(methylene)-, (1S,5R,9R)-
CAS No.:19431-79-9
Molecular Formula:C15H24O
Molecular Weight:220.35000
Hs Code.:
Mol file:19431-79-9.mol

Synonyms:(1R,5R,9S)-caryophylla-4(12),8(13)-dien-5-ol;caryophylla-4(12),8(13)-dien-5β-ol;(1R,5R,9S)-caryophylla-4-(12),8(13)-dien-5-ol;5α-hydroxycaryophylla-4(12),8(13)-diene;caryophylla-2(12),6(13)-dien-5β-ol;(1S,5R,9R)-10,10-Dimethyl-2,6-dimethylene-bicyclo[7.2.0]undecan-5-ol;caryophylla-4(12),8(13)-dien-5α-ol;

Suppliers and Price of Bicyclo[7.2.0]undecan-5-ol, 10,10-dimethyl-2,6-bis(methylene)-, (1S,5R,9R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bicyclo[7.2.0]undecan-5-ol, 10,10-dimethyl-2,6-bis(methylene)-, (1S,5R,9R)-

Chemical Property:

Boiling Point:310.4±31.0 °C(Predicted)
PSA：20.23000
Density:0.96±0.1 g/cm3(Predicted)
LogP:3.69600

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Bicyclo[7.2.0]undecan-5-ol, 10,10-dimethyl-2,6-bis(methylene)-, (1S,5R,9R)-

There total 4 articles about Bicyclo[7.2.0]undecan-5-ol, 10,10-dimethyl-2,6-bis(methylene)-, (1S,5R,9R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 1139-30-6,13877-94-6,17627-43-9,60594-22-1,60594-23-2,68832-36-0,103475-43-0,119818-36-9,119818-37-0
caryophyllene epoxide

: 88514-10-7
((1S,8R)-4,10,10-Trimethyl-7-methylene-bicyclo[6.2.0]dec-4-yl)-methanol

: 19431-76-6,19431-77-7,32214-88-3,32214-89-4,34298-31-2,38284-08-1,73088-51-4
caryophyllenol-I

: 19431-79-9,19431-80-2,38284-26-3
(1S,5S,9R)-10,10-Dimethyl-2,6-dimethylene-bicyclo[7.2.0]undecan-5-ol

Guidance literature:: With aluminum oxide; In hexane; for 14h;
DOI:10.1016/S0040-4020(01)91590-X

Reference yield:

: 19431-79-9,19431-80-2,38284-26-3
(5R,9R)-10,10-Dimethyl-2,6-dimethylene-bicyclo[7.2.0]undecan-5-ol

Guidance literature:: Verb. XV, Triphenylphosphinmethylen (aus Methyl-triphenylphosphoniumiodid und Phenyllithium in sd. Diethylether/THF), sd. Diethylether/THF;
DOI:10.1139/v64-249

Reference yield:

: 61824-50-8
(Z)-(1R,9S)-4,11,11-Trimethyl-8-methylene-bicyclo[7.2.0]undec-3-en-5-one

: 19431-79-9,19431-80-2,38284-26-3
(1S,5S,9R)-10,10-Dimethyl-2,6-dimethylene-bicyclo[7.2.0]undecan-5-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 3 mg / LiAlH₄ / diethyl ether / 2 h / Ambient temperature

2: 79 percent / m-chloroperbenzoic acid / CHCl₃ / 6 h / 0 °C

3: 63 percent / Al₂O₃ / hexane / 14 h

With aluminum oxide; lithium aluminium tetrahydride; 3-chloro-benzenecarboperoxoic acid; In diethyl ether; hexane; chloroform;
DOI:10.1016/S0040-4020(01)91590-X