(3-Iodo-2,4,6-trimethylphenyl)bis(2,4,6-trimethylphenyl)phosphane

Base Information

Chemical Name:(3-Iodo-2,4,6-trimethylphenyl)bis(2,4,6-trimethylphenyl)phosphane
CAS No.:197144-69-7
Molecular Formula:C27H32IP
Molecular Weight:514.429
Hs Code.:
DSSTox Substance ID:DTXSID00571543
Wikidata:Q82459645
Mol file:197144-69-7.mol

Synonyms:197144-69-7;(3-Iodo-2,4,6-trimethylphenyl)bis(2,4,6-trimethylphenyl)phosphane;DTXSID00571543

Suppliers and Price of (3-Iodo-2,4,6-trimethylphenyl)bis(2,4,6-trimethylphenyl)phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3-Iodo-2,4,6-trimethylphenyl)bis(2,4,6-trimethylphenyl)phosphane

Chemical Property:

XLogP3:8.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:514.12864
Heavy Atom Count:29
Complexity:481

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C(=C1)C)P(C2=C(C=C(C=C2C)C)C)C3=C(C(=C(C=C3C)C)I)C)C

Technology Process of (3-Iodo-2,4,6-trimethylphenyl)bis(2,4,6-trimethylphenyl)phosphane

There total 1 articles about (3-Iodo-2,4,6-trimethylphenyl)bis(2,4,6-trimethylphenyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 197144-71-1
(3-Bromo-2,4,6-trimethyl-phenyl)-bis-(2,4,6-trimethyl-phenyl)-phosphane

: 197144-69-7
(3-Iodo-2,4,6-trimethyl-phenyl)-bis-(2,4,6-trimethyl-phenyl)-phosphane

Guidance literature:: With n-butyllithium; iodine; Yield given. Multistep reaction; 1) THF, -78 deg C, 2) THF, -78 deg C;
DOI:10.1016/S0040-4039(97)01711-5

Reference yield: 66.0%

: 4627-22-9
bis(4-tert-butylphenyl)amine

: 197144-69-7
(3-Iodo-2,4,6-trimethyl-phenyl)-bis-(2,4,6-trimethyl-phenyl)-phosphane

: {3-[Bis-(2,4,6-trimethyl-phenyl)-phosphanyl]-2,4,6-trimethyl-phenyl}-bis-(4-tert-butyl-phenyl)-amine

Guidance literature:: With 18-crown-6 ether; copper; potassium carbonate; In various solvent(s); for 120h; Heating;
DOI:10.1016/S0040-4039(97)01711-5

Reference yield:

: 197144-69-7
(3-Iodo-2,4,6-trimethyl-phenyl)-bis-(2,4,6-trimethyl-phenyl)-phosphane

: {3-[Bis-(2,4,6-trimethyl-phenyl)-phosphinoyl]-2,4,6-trimethyl-phenyl}-bis-(4-tert-butyl-phenyl)-amine

Guidance literature:: Multi-step reaction with 2 steps

1: 66 percent / Cu, K₂CO₃, 18-crown-6 / various solvent(s) / 120 h / Heating

2: oxidation

With 18-crown-6 ether; copper; potassium carbonate; In various solvent(s);
DOI:10.1016/S0040-4039(97)01711-5