(2-Methoxy-4-methylphenyl)boronic acid

Base Information

Chemical Name:(2-Methoxy-4-methylphenyl)boronic acid
CAS No.:198211-79-9
Molecular Formula:C8H11BO3
Molecular Weight:165.985
Hs Code.:
European Community (EC) Number:844-754-6
DSSTox Substance ID:DTXSID80593561
Nikkaji Number:J2.613.187A
Wikidata:Q82488062
Mol file:198211-79-9.mol

Synonyms:(2-Methoxy-4-methylphenyl)boronic acid;198211-79-9;2-METHOXY-4-METHYLPHENYLBORONIC ACID;Boronic acid, (2-methoxy-4-methylphenyl)- (9CI);MFCD18072608;Boronic acid, B-(2-methoxy-4-methylphenyl)-;SCHEMBL1228414;DTXSID80593561;LWNWZQJRSFHZRG-UHFFFAOYSA-N;2-Methoxy-4-methylphenylboronicacid;4-methyl-2-methoxylphenylboronic acid;AKOS016842752;(2-methoxy 4-methyl phenyl)boronic acid;SY198433;DB-010459;CS-0175800;D71595;EN300-213319;A879992;Z1255503201

Suppliers and Price of (2-Methoxy-4-methylphenyl)boronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
(2-Methoxy-4-methylphenyl)boronicacid 95+%
1g
$ 748.00

AOBChem
2-Methoxy-4-methylphenylboronicacid 97%
5g
$ 800.00

American Custom Chemicals Corporation
(2-METHOXY-4-METHYLPHENYL)BORONIC ACID 95.00%
5MG
$ 499.54

American Custom Chemicals Corporation
(2-METHOXY-4-METHYLPHENYL)BORONIC ACID 95.00%
1G
$ 1529.85

Alichem
2-Methoxy-4-methylphenylboronicacid
500mg
$ 1019.20

AK Scientific
2-Methoxy-4-methylphenylboronicacid
5g
$ 2638.00

Total 8 raw suppliers

Chemical Property of (2-Methoxy-4-methylphenyl)boronic acid

Chemical Property:

Boiling Point:330.9±52.0 °C(Predicted)
PKA:8.87±0.58(Predicted)
PSA：49.69000
Density:1.14±0.1 g/cm3(Predicted)
LogP:-0.31660
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:166.0801244
Heavy Atom Count:12
Complexity:140

Purity/Quality:

97% ^*data from raw suppliers

(2-Methoxy-4-methylphenyl)boronicacid 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=C(C=C(C=C1)C)OC)(O)O

Technology Process of (2-Methoxy-4-methylphenyl)boronic acid

There total 9 articles about (2-Methoxy-4-methylphenyl)boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 186583-59-5
1-iodo-2-methoxy-4-methylbenzene

: 198211-79-9
(2-methoxy-4-methylphenyl)boronic acid

Guidance literature:: 1-iodo-2-methoxy-4-methylbenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.0833333h; Inert atmosphere;

With Trimethyl borate; In tetrahydrofuran; diethyl ether; hexane; at -50 ℃; for 0.5h; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; diethyl ether; hexane; water; at 20 ℃;
DOI:10.1246/bcsj.20110309

Reference yield: 23.0%

: 95740-49-1
1-bromo-2-methoxy-4-methylbenzene

: 198211-79-9
(2-methoxy-4-methylphenyl)boronic acid

Guidance literature:: 1-bromo-2-methoxy-4-methylbenzene; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 0.166667h; Inert atmosphere;

With Trimethyl borate; In tetrahydrofuran; pentane; at -78 - 20 ℃; for 2h;

With ammonium chloride; In tetrahydrofuran; pentane;

Reference yield: 11.0%

: 121-43-7,63156-11-6
Trimethyl borate

: 95740-49-1
1-bromo-2-methoxy-4-methylbenzene

: 198211-79-9
(2-methoxy-4-methylphenyl)boronic acid

Guidance literature:: 1-bromo-2-methoxy-4-methylbenzene; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 0.166667h; Inert atmosphere;

Trimethyl borate; In tetrahydrofuran; pentane; at -78 ℃; for 1h;