Technology Process of Anisole, o-octyl-
There total 9 articles about Anisole, o-octyl- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium hydroxide; dihydrogen peroxide;
cis-dichloro-1,1'-bis(diphenylphosphino)ferrocene palladium(II);
In
tetrahydrofuran;
To a soln. of 9-octyl-9-BBN is added C6H4(OCH3)I, THF and aq. NaOH at room temp., mixt. refluxed overnight (14-16 h), react. mixt. diluted with hexane or benzene, residue oxidized by H2O2 at room temp.; Extracted, washed with brine, dried (MgSO4), when a product is sensitive to NaOH/H2O, the extract is subjected to column chromy., final product is identified by mass spectrometry, IR, elem. anal.;
DOI:10.1021/ja00183a048
- Guidance literature:
-
oct-1-ene;
With
9-borabicyclo[3.3.1]nonane dimer;
In
tetrahydrofuran;
at 20 ℃;
for 17h;
4-iodoanisol;
With
potassium phosphate; 2H(1+)*Cl4Pd(2-)*2H3N; poly[N-isopropylacrylamide-co-diphenyl(4'-styryl)phosphine];
In
tetrahydrofuran; 1,4-dioxane;
at 100 ℃;
for 1.5h;
DOI:10.1021/jo034354v
- Guidance literature:
-
With
N,N,N'N'-tetramethyl-1,3-propanediamine; 1,3-bis(mesityl)imidazolium chloride; cobalt(II) chloride;
In
diethyl ether;
at 25 ℃;
for 1h;
Inert atmosphere;
DOI:10.1246/cl.2008.1178
