Aluminum, diethoxyhydro-

Base Information

• Chemical Name: Aluminum, diethoxyhydro-
• CAS No.: 20204-36-8
• Molecular Formula: C4H11AlO2
• Molecular Weight: 118.112
• Mol file: 20204-36-8.mol

Synonyms:

Chemical Property of Aluminum, diethoxyhydro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Aluminum, diethoxyhydro-

There total 2 articles about Aluminum, diethoxyhydro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

lithium monoethoxyaluminum hydride (26522-31-6) + (1R,2R)-(-)-ethyl trans-(2-methylcyclohexyl)-n-pentylborinate (83681-53-2) → diethoxyaluminum hydride (20204-36-8) + lithium (1S,2S)-trans-(2-methylcyclohexyl)-n-pentylborohydride

Guidance literature:

In further solvent(s); addn. of soln. of borinate in ethyl ether to a soln. of LiAlH3(OEt) (prepd. from LiAlH4 and ethylacetate at 25°C) in ethyl ether at 0°C under N2 with const. stirring; centrifugation, washing of (EtO)2AlH with ethyl ether, evapn. in vac., dissolving in THF;

DOI:10.1021/ja00288a031

Reference yield: 72.0%

lithium monoethoxyaluminum hydride (26522-31-6) + ethyl erythro-(2S,3R)-3-phenyl-2-pentyl-n-pentylborinate → diethoxyaluminum hydride (20204-36-8) + lithium (2S,3R)-erythro-3-phenyl-2-pentyl-n-pentylborohydride

Guidance literature:

In further solvent(s); addn. of soln. of borinate in ethyl ether to a soln. of LiAlH3(OEt) (prepd. from LiAlH4 and ethylacetate at 25°C) in ethyl ether at 0°C under N2 with const. stirring; centrifugation, washing of (EtO)2AlH with ethyl ether, evapn. in vac., dissolving in THF;

DOI:10.1021/ja00288a031

upstream raw materials:

lithium monoethoxyaluminum hydride

(1R,2R)-(-)-ethyl trans-(2-methylcyclohexyl)-n-pentylborinate