3H-Indolium, 1-butyl-2,3,3-trimethyl-, iodide

Base Information

• Chemical Name: 3H-Indolium, 1-butyl-2,3,3-trimethyl-, iodide
• CAS No.: 20205-30-5
• Molecular Formula: C15H22N.I
• Molecular Weight: 343.251
• Mol file: 20205-30-5.mol

Synonyms:1,1,2-trimethyl-3-butylbenzindoline iodide;F1029-0077;3H-Indolium,1-butyl-2,3,3-trimethyl-,iodide;1-butyl-2,3,3-trimethyl-3-hydroindole,iodide;2,3,3-trimethyl-3H-indol-1-ium iodide;1-butyl-2,3,3-trimethyl-3H-indolium iodide;1-butyl-2,3,3-trimethyl-3H-indol-1-ium iodide;1-butyl-2,3,3-trimethylindolium iodide;iodure de 1-butyl 2,3,3-trimethylindoleninium;

Chemical Property of 3H-Indolium, 1-butyl-2,3,3-trimethyl-, iodide

Chemical Property:

• Melting Point: 102 °C(Solv: ethyl acetate (141-78-6))
• PSA: 3.01000
• LogP: 0.84560

Purity/Quality:

99% ^*data from raw suppliers

1-Butyl-2,3,3-trimethyl-3H-indol-1-ium iodide 95%+ ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3H-Indolium, 1-butyl-2,3,3-trimethyl-, iodide

There total 6 articles about 3H-Indolium, 1-butyl-2,3,3-trimethyl-, iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2,3,3-trimethylindoleniune (1640-39-7) + 1-iodo-butane (542-69-8) → N-butyl-2,3,3-trimethylindoleninium iodide (20205-30-5)

Guidance literature:

In acetonitrile; for 2h; Reflux;

Reference yield:

3-methyl-butan-2-one (563-80-4) → N-butyl-2,3,3-trimethylindoleninium iodide (20205-30-5)

Guidance literature:

Multi-step reaction with 2 steps

1: acetic acid / 16 h / 120 °C

2: butanone / 12 h / Reflux

With acetic acid; butanone; 1: |Fischer Indole Synthesis;

DOI:10.1002/cmdc.201300090

Reference yield:

phenylhydrazine hydrochloride (59-88-1) → N-butyl-2,3,3-trimethylindoleninium iodide (20205-30-5)

Guidance literature:

Multi-step reaction with 2 steps

1: acetic acid / Reflux

2: acetonitrile / 72 h / Reflux

With acetic acid; In acetonitrile;

DOI:10.3390/molecules181113588

upstream raw materials:

2,3,3-trimethylindoleniune

1-iodo-butane

1-Iodooctane

phenylhydrazine hydrochloride

Downstream raw materials:

C₂₆H₂₄N₄

C₂₃H₂₉ClNO⁽¹⁺⁾*I^(1-)

2-[2-chloro-3-[2-(1,3-dihydro-1-butyl-3,3-dimethyl-2H-indolidine)ethyl-1-cyclohexyl]ethyl-5-(4-diethylamino)benzene]-1-butyl-3,3-dimethylindoline iodide

1-butyl-2-((1E,3E)-3-(1-butyl-3,3-dimethylindolin-2-ylidene)prop-1-enyl)-3,3-dimethyl-3H-indolium iodide