Benzene, 1-(1-bromo-2,2-difluoroethenyl)-2-methyl-

Base Information

Chemical Name:Benzene, 1-(1-bromo-2,2-difluoroethenyl)-2-methyl-
CAS No.:202207-41-8
Molecular Formula:C9H7BrF2
Molecular Weight:233.055
Hs Code.:
DSSTox Substance ID:DTXSID90443447
Nikkaji Number:J946.805F

Synonyms:Benzene, 1-(1-bromo-2,2-difluoroethenyl)-2-methyl-;202207-41-8;DTXSID90443447;1-Methyl-2-(1-bromo-2,2-difluorovinyl)benzene

Suppliers and Price of Benzene, 1-(1-bromo-2,2-difluoroethenyl)-2-methyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzene, 1-(1-bromo-2,2-difluoroethenyl)-2-methyl-

Chemical Property:

XLogP3:3.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:231.96992
Heavy Atom Count:12
Complexity:185

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=CC=C1C(=C(F)F)Br

Technology Process of Benzene, 1-(1-bromo-2,2-difluoroethenyl)-2-methyl-

There total 2 articles about Benzene, 1-(1-bromo-2,2-difluoroethenyl)-2-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 615-37-2
ortho-methylphenyl iodide

: 421-06-7
2-bromo-1,1,1-trifluoroethane

: 202207-41-8
o-methyl-α-bromo-β,β-difluorostyrene

Guidance literature:: 2-bromo-1,1,1-trifluoroethane; With zinc(II) chloride; lithium diisopropyl amide; In tetrahydrofuran; at 20 ℃; for 2h;

ortho-methylphenyl iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 60 ℃; for 12h;
DOI:10.1016/j.jfluchem.2003.11.029

Reference yield: 81.0%

: 615-37-2
ortho-methylphenyl iodide

: 202207-41-8
o-methyl-α-bromo-β,β-difluorostyrene

Guidance literature:: With tris(triphenylphosphano)palladium; In N,N-dimethyl-formamide; at 60 ℃; for 10h;
DOI:10.1021/jo971554w

Reference yield: 91.0%

: 1765-93-1
4-fluoroboronic acid

: 202207-41-8
o-methyl-α-bromo-β,β-difluorostyrene

: 2-(4-fluorophenyl)-2-(2-methylphenyl)-1,1-difluoroethene

: 398-23-2
4,4'-difluorobiphenyl

Guidance literature:: With potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In ethanol; water; benzene; for 24h; Heating;
DOI:10.1021/jo051842p