CID 6333604

Base Information

• Chemical Name: CID 6333604
• CAS No.: 20224-83-3
• Molecular Formula: C18H15AuN3P
• Molecular Weight: 501.277
• NSC Number: 274556
• Mol file: 20224-83-3.mol

Synonyms:20224-83-3;NSC274556;NSC-274556

Chemical Property of CID 6333604

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 503.082580
• Heavy Atom Count: 23
• Complexity: 288

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.N=[N+]=[N-].[Au+]

Technology Process of CID 6333604

There total 4 articles about CID 6333604 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(Ph3P)gold(I)OtBu (106734-50-3) + trimethylsilylazide (4648-54-8) → PPh3AuIC8H5 (20224-83-3)

Guidance literature:

In tetrahydrofuran; (N2), Au complex and THF at room temp. treated under stirring with 5 equiv. of Me3SiN3 in THF, reacted for 5 h; filtered (celite), evapd.(vac.), washed (hexanes), filtered, dried (vac.);

DOI:10.1002/ejic.200900034

Reference yield: 79.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + trimethylsilylazide (4648-54-8) → PPh3AuIC8H5 (20224-83-3)

Guidance literature:

With Tl(CH₃C(O)CHC(O)CH₃); In methanol; toluene; Tl compd. (1.05 equiv.) was added to suspn. of Au complex in toluene; reacted for 4 h; filtered through Celite; azide was added to filtrate; MeOH was added; stirred for 20 h; filtered through Celite; concd. (vac.); pentane added; elem. anal.;

DOI:10.1021/om0607200

Reference yield: 50.0%

→ PPh3AuIC8H5 (20224-83-3)

Guidance literature:

With thallium(I) 2,4-pentanedionate; In toluene; at 20 ℃; for 4h; Darkness;

In methanol; toluene; at 20 ℃; for 18h; Darkness;

upstream raw materials:

(triphenylphosphine)gold(I) chloride

trimethylsilylazide

(Ph₃P)gold(I)OtBu

Downstream raw materials:

Co(carbonyl)4(PPh₃)gold

{((C₆H₅)3PAu)6Mn(CO)3}⁽¹⁺⁾*PF₆^(1-) = {((C₆H₅)3PAu)6Mn(CO)3}PF₆