Hydroperoxide, 1-methyl-2-propenyl

Base Information

• Chemical Name: Hydroperoxide, 1-methyl-2-propenyl
• CAS No.: 20733-08-8
• Molecular Formula: C4H8O2
• Molecular Weight: 88.1063
• DSSTox Substance ID: DTXSID60440589
• Nikkaji Number: J1.480.844B
• Mol file: 20733-08-8.mol

Synonyms:Hydroperoxide, 1-methyl-2-propenyl;20733-08-8;1-Methylallyl hydroperoxide;DTXSID60440589

Chemical Property of Hydroperoxide, 1-methyl-2-propenyl

Chemical Property:

• XLogP3: 0.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 88.052429494
• Heavy Atom Count: 6
• Complexity: 42.8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C=C)OO

Technology Process of Hydroperoxide, 1-methyl-2-propenyl

There total 1 articles about Hydroperoxide, 1-methyl-2-propenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-hydroxy-3-butene (598-32-3) → 1-methylallyl sulfate + hydroperoxide de 1-methyl-prop-2-enyle (20733-08-8) + 1-methylallyl hydrogen peroxysulfate (1642887-91-9) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2)

Guidance literature:

With sulfuric acid; dihydrogen peroxide; In water; at 24.84 ℃; for 2h; Kinetics;

DOI:10.1039/c4ra02486a

Reference yield: 54.0%

hydroperoxide de 1-methyl-prop-2-enyle (20733-08-8) → butane-1,2,3-triol (4435-50-1)

Guidance literature:

With osmium(VIII) oxide; 2-((1S)-(6-methoxyquinolin-4-yl)((trimethylsilyl)oxy)methyl)5-vinylquinuclidine; water; In acetone; at 0 ℃; for 1h; enantioselective reaction;

DOI:10.3906/kim-1411-68

upstream raw materials:

2-hydroxy-3-butene

Downstream raw materials:

butane-1,2,3-triol