Cyclopentylidenehydrazine

Base Information

• Chemical Name: Cyclopentylidenehydrazine
• CAS No.: 10080-41-8
• Molecular Formula: C5H10 N2
• Molecular Weight: 98.1478
• NSC Number: 75983
• DSSTox Substance ID: DTXSID20291498
• Mol file: 10080-41-8.mol

Synonyms:10080-41-8;cyclopentylidenehydrazine;cyclopentanone hydrazone;NSC75983;Cyclopentylidene-hydrazine;DTXSID20291498;HUFXTMLATKDGEI-UHFFFAOYSA-N;NSC-75983

Chemical Property of Cyclopentylidenehydrazine

Chemical Property:

• Vapor Pressure: 0.529mmHg at 25°C
• Boiling Point: 190.9°Cat760mmHg
• Flash Point: 69.2°C
• Density: 1.14g/cm³
• XLogP3: 0.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 98.084398327
• Heavy Atom Count: 7
• Complexity: 78.1

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(=NN)C1

Technology Process of Cyclopentylidenehydrazine

There total 2 articles about Cyclopentylidenehydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

cyclopentanone (120-92-3) → cyclopentanone hydrazone (10080-41-8)

Guidance literature:

With hydrazine hydrate; for 16h; Heating;

DOI:10.1021/jo026663b

Reference yield: 61.0%

→ cyclopentanone hydrazone (10080-41-8)

Guidance literature:

Reference yield: 80.0%

cyclopentanone hydrazone (10080-41-8) + methyl 2-chloro-2-(2-phenylhydrazono)acetate (58131-64-9) → C14H18N4O2

Guidance literature:

With triethylamine; In tetrahydrofuran; Ambient temperature;

upstream raw materials:

cyclopentanone

Downstream raw materials:

Cyclopentane

cyclopentylhydrazine

3-(4-Nitro-phenyl)-1-oxa-2,4-diaza-spiro[4.4]non-2-en-4-ylamine

{(R)-2-[(R)-3-Benzyloxy-2-dibenzylamino-prop-(Z)-ylidene]-cyclopentyl}-methanol

Refernces

• 1、 Holton, Terrence L.,Shechter, Harold. "Advantageous Syntheses of Diazo Compounds by Oxidation of Hydrazones with Lead Tetraacetate in Basic Environments". . p. 4725 - 4729. Retrieved 1995.
• 2、 Cheung, Lawrence L. W.,Yudin, Andrei K.. "Synthesis of highly substituted cyclobutane fused-ring systems from n-vinyl β-lactams through a one-pot domino process". supporting information; experimental part. p. 4100 - 4109. Retrieved 2010/07/05.
• 3、 -. "Oxadiazoline ligands for modulating the expression of exogenous genes via an ecdysone receptor complex". Page/Page column 27. . Retrieved 2008/06/13.