Bis(4-bromobenzyl)sulfide

Base Information

• Chemical Name: Bis(4-bromobenzyl)sulfide
• CAS No.: 20883-11-8
• Molecular Formula: C14H12Br2S
• Molecular Weight: 372.123
• DSSTox Substance ID: DTXSID00490144
• Nikkaji Number: J3.491.876G
• Wikidata: Q82333776
• Mol file: 20883-11-8.mol

Synonyms:bis(4-bromobenzyl)sulfide;20883-11-8;SCHEMBL9344493;DTXSID00490144;OHTWKJSDUZIJBN-UHFFFAOYSA-N;1,1'-[Sulfanediylbis(methylene)]bis(4-bromobenzene)

Chemical Property of Bis(4-bromobenzyl)sulfide

Chemical Property:

• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 371.90060
• Heavy Atom Count: 17
• Complexity: 184

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC(=CC=C1CSCC2=CC=C(C=C2)Br)Br

Technology Process of Bis(4-bromobenzyl)sulfide

There total 7 articles about Bis(4-bromobenzyl)sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-bromomethyl-4-bromobenzene (589-15-1) → (4-bomophenyl)(methyl)sulfide (20883-11-8)

Guidance literature:

With dithiooxamide; sodium hydroxide; In water; at 30 - 35 ℃; for 0.5h; Green chemistry;

DOI:10.1002/ejoc.201500156

Reference yield: 85.0%

p-bromophenylmethyl sulfoxide (174213-85-5) → (4-bomophenyl)(methyl)sulfide (20883-11-8)

Guidance literature:

With iodine; sodium hydrogensulfite; In chloroform; at 20 ℃; for 3h; Temperature;

DOI:10.1016/j.tetlet.2015.10.035

Reference yield: 85.0%

→ (4-bomophenyl)(methyl)sulfide (20883-11-8)

Guidance literature:

With sodiumsulfide nonahydrate; In acetonitrile; at 85 ℃; for 24h; Sealed tube;

upstream raw materials:

1-bromomethyl-4-bromobenzene

-benzyl-disulfid

p-bromophenylmethyl sulfoxide

4-bromobenzenemethanol

Downstream raw materials:

bis-(4-dihydroxyborylbenzyl)sulfide

2,5-bis-(4-bromo-phenyl)-1,1-dioxo-1λ⁶-thiophene-3,4-diol

4-(4-Bromothiobenzoyl)morpholine

bis-(4-bromo-benzyl)-sulfone