4-(2,4-Dimethylbenzene-1-sulfinyl)-2,3-dihydrofuran

Base Information

Chemical Name:4-(2,4-Dimethylbenzene-1-sulfinyl)-2,3-dihydrofuran
CAS No.:211310-22-4
Molecular Formula:C12H14O2S
Molecular Weight:222.308
Hs Code.:
DSSTox Substance ID:DTXSID10578720
Nikkaji Number:J1.020.285J

Synonyms:211310-22-4;4-(2,4-Dimethylbenzene-1-sulfinyl)-2,3-dihydrofuran;DTXSID10578720;4-((2,4-Dimethylphenyl)sulfinyl)-2,3-dihydrofuran

Suppliers and Price of 4-(2,4-Dimethylbenzene-1-sulfinyl)-2,3-dihydrofuran

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-(2,4-Dimethylbenzene-1-sulfinyl)-2,3-dihydrofuran

Chemical Property:

XLogP3:2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:222.07145086
Heavy Atom Count:15
Complexity:285

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C=C1)S(=O)C2=COCC2)C

Technology Process of 4-(2,4-Dimethylbenzene-1-sulfinyl)-2,3-dihydrofuran

There total 2 articles about 4-(2,4-Dimethylbenzene-1-sulfinyl)-2,3-dihydrofuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 211310-46-2
4-(2,4-dimethyl-phenylsulfanyl)-2,3-dihydro-furan

: 211310-22-4
4-[(2,4-Dimethyl)phenylsulfinyl]-2,3-dihydrofuran

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 ℃;
DOI:10.1002/1521-3765(20010917)7:18<3890::AID-CHEM3890>3.0.CO;2-Y

Reference yield:

: 211310-44-0
(2,4-dimethylphenyl)methylsulfoxide

: 211310-22-4
4-[(2,4-Dimethyl)phenylsulfinyl]-2,3-dihydrofuran

Guidance literature:: Multi-step reaction with 2 steps

1.1: (CF₃CO)2O / CH₂Cl₂ / 0.25 h / -78 °C

1.2: CH₂Cl₂ / 0.25 h / -78 °C

1.3: 65 percent / Et₃N / CH₂Cl₂ / -78 - 20 °C

2.1: 40 percent / MCPBA / CH₂Cl₂ / -78 °C

With 3-chloro-benzenecarboperoxoic acid; trifluoroacetic anhydride; In dichloromethane;
DOI:10.1002/1521-3765(20010917)7:18<3890::AID-CHEM3890>3.0.CO;2-Y

Reference yield:

: 591-50-4
iodobenzene

: 211310-22-4
4-[(2,4-Dimethyl)phenylsulfinyl]-2,3-dihydrofuran

: (2S*,SR*)-3-(2,4-Dimethylphenylsulfinyl)-2-phenyl-2,5-dihydrofuran

: (2R*,SR*)-3-(2,4-Dimethylphenylsulfinyl)-2-phenyl-2,5-dihydrofuran

Guidance literature:: With palladium diacetate; 1,3-bis-(diphenylphosphino)propane; silver carbonate; In N,N-dimethyl-formamide; at 100 ℃; Yield given. Yields of byproduct given;
DOI:10.1021/ja980858c