1-Chloro-4-(cyclopropylidenemethyl)benzene

Base Information

• Chemical Name: 1-Chloro-4-(cyclopropylidenemethyl)benzene
• CAS No.: 214116-80-0
• Molecular Formula: C10H9Cl
• Molecular Weight: 164.634
• DSSTox Substance ID: DTXSID50402338
• Nikkaji Number: J1.154.231J
• Mol file: 214116-80-0.mol

Synonyms:1-chloro-4-(cyclopropylidenemethyl)benzene;214116-80-0;4-Chlorobenzylidenecyclopropane;SCHEMBL15282036;DTXSID50402338;CPAJPJITPOUPAT-UHFFFAOYSA-N

Chemical Property of 1-Chloro-4-(cyclopropylidenemethyl)benzene

Chemical Property:

• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 164.0392780
• Heavy Atom Count: 11
• Complexity: 158

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC1=CC2=CC=C(C=C2)Cl

Technology Process of 1-Chloro-4-(cyclopropylidenemethyl)benzene

There total 6 articles about 1-Chloro-4-(cyclopropylidenemethyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

3-bromopropyltriphenylphosphonium bromide (3607-17-8) + 4-chlorobenzaldehyde (104-88-1) → 1-chloro-4-(cyclopropylidenemethyl)benzene (214116-80-0)

Guidance literature:

3-bromopropyltriphenylphosphonium bromide; With sodium hydride; In tetrahydrofuran; at 70 ℃; for 12h; Inert atmosphere;

4-chlorobenzaldehyde; In tetrahydrofuran; at 70 ℃; Inert atmosphere;

DOI:10.1021/acs.orglett.5b02940

Reference yield: 48.0%

(1-Benzotriazol-1-yl-cyclopropyl)-(4-chloro-phenyl)-methanol → 1-chloro-4-(cyclopropylidenemethyl)benzene (214116-80-0)

Guidance literature:

With titanium; triethylamine; In 1,2-dimethoxyethane; at 60 ℃; for 12h;

DOI:10.1021/jo980617n

Reference yield: 46.0%

(1-Benzotriazol-2-yl-cyclopropyl)-(4-chloro-phenyl)-methanol → 1-chloro-4-(cyclopropylidenemethyl)benzene (214116-80-0)

Guidance literature:

With titanium; triethylamine; In 1,2-dimethoxyethane; at 60 ℃; for 12h;

DOI:10.1021/jo980617n

upstream raw materials:

4-chlorobenzaldehyde

pentachlorophenyl cyclopropyl sulfone

3-bromopropyltriphenylphosphonium bromide

4-bromobutylphosphonium bromide

Downstream raw materials:

1-Chloro-4-((Z)-2-iodo-4-phenylselanyl-but-1-enyl)-benzene

1-Chloro-4-((Z)-2,4-diiodo-but-1-enyl)-benzene

C₃₁H₂₅ClO

C₁₆H₁₂ClN₃O₂

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 214116-80-0 Benzene, 1-chloro-4-(cyclopropylidenemethyl)-

Send

Send

Metric Ton KG G Pound L ML

Send

Send