methoxyrheniumtrioxide

Base Information

• Chemical Name: methoxyrheniumtrioxide
• CAS No.: 44252-75-7
• Molecular Formula: CH₃O₄Re
• Molecular Weight: 265.239
• Mol file: 44252-75-7.mol

Synonyms:

Chemical Property of methoxyrheniumtrioxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methoxyrheniumtrioxide

There total 4 articles about methoxyrheniumtrioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

fac-(CO)3(1,3-bis(diphenylphosphino)propane)ReOCH3 (478917-34-9) + rhenium(VII) oxide → methoxyrheniumtrioxide (44252-75-7) + fac-(CO)3(1,3-bis(diphenylphosphino)propane)ReOReO3

Guidance literature:

In dichloromethane; under N2; mixt. of Re complex and Re2O7 (molar ratio 1:1) in CH2Cl2 stirred at ambient temp. for 30 min; monitored by IR spectra; solvent removed on rotary evaporator; extd. with CH2Cl2; evapd. to dryness; recrystd. from CH2Cl2-hexane at -5°C; filtered;

DOI:10.1016/S0022-328X(02)01632-7

Reference yield:

fac-tricarbonyl(1,3-bis(diphenylphosphino)propane)methylcarbonatorhenium(I) (386704-95-6) + rhenium(VII) oxide → methoxyrheniumtrioxide (44252-75-7) + fac-(CO)3(1,3-bis(diphenylphosphino)propane)ReOReO3

Guidance literature:

In dichloromethane; byproducts: CO2; under N2; mixt. of Re complex and Re2O7 (molar ratio 1:1) in CH2Cl2 stirred at 0°C for 30 min; monitored by IR spectra; solvent removed on rotary evaporator; recrystd.from CH2Cl2-hexane at -5°C; filtered;

DOI:10.1016/S0022-328X(02)01632-7

Reference yield:

fac-(CO)3(1,2-bis(diphenylphosphino)ethane)Mn(OCH3) (133872-67-0) + rhenium(VII) oxide → methoxyrheniumtrioxide (44252-75-7) + fac-(CO)3(1,2-bis(diphenylphosphino)ethane)MnOReO3

Guidance literature:

In dichloromethane; under N2; mixt. of Mn complex and Re2O7 (molar ratio 1:1) in CH2Cl2 stirred at ambient temp. for 30 min; monitored by IR spectra; solvent removed on rotary evaporator; extd. with CH2Cl2; evapd. to dryness; recrystd. from CH2Cl2-hexane at -5°C; filtered;

DOI:10.1016/S0022-328X(02)01632-7

upstream raw materials:

fac-(CO)3(1,3-bis(diphenylphosphino)propane)ReOCH₃

fac-tricarbonyl(1,3-bis(diphenylphosphino)propane)methylcarbonatorhenium(I)

fac-(CO)3(1,2-bis(diphenylphosphino)ethane)Mn(OCH₃)

fac-(CO)3(1,2-bis(diphenylphosphino)ethane)Re(OCH₃)