1-Phenyl-2,4-cyclohexadiene

Base Information

• Chemical Name: 1-Phenyl-2,4-cyclohexadiene
• CAS No.: 21473-05-2
• Molecular Formula: C12H12
• Molecular Weight: 156.227
• Hs Code.: 2902909090
• Mol file: 21473-05-2.mol

Synonyms:5-Phenyl-1,3-cyclohexadien;cyclohexa-2,4-dienylbenzene;2,4-Cyclohexadien-1-ylbenzene;1,2-Dihydrobiphenyl;1-cyclohexa-2,4-dienyl-benzene;5-phenylcyclohexa-1,3-diene;Benzene,2,4-cyclohexadien-1-yl;6-phenyl-1,3-cyclohexadiene;1-Phenyl-2,4-cyclohexadien;

Chemical Property of 1-Phenyl-2,4-cyclohexadiene

Chemical Property:

• Boiling Point: 234.9±15.0 °C(Predicted)
• PSA: 0.00000
• Density: 0.993±0.06 g/cm3(Predicted)
• LogP: 3.28630

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Phenyl-2,4-cyclohexadiene

There total 21 articles about 1-Phenyl-2,4-cyclohexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(C6H7(C6H5))Mn(CO)(NO)(P(CH3)3) + (C6H7(C6H5))Mn(CO)(NO)(P(CH3)3) → 1-phenylcyclohexa-2,4-diene (21473-05-2)

Guidance literature:

With FeCl₃; In tetrahydrofuran; excess FeCl3, 25°C, reaction time: 1 h; removal of solvent, addn. of HCl, extn. (CH2Cl2);

DOI:10.1021/ja00204a046

Reference yield: 85.0%

(1S,6R)-2-Acetoxy-6-phenyl-cyclohex-3-enecarboxylic acid (74502-11-7,74524-50-8) → 1-phenylcyclohexa-2,4-diene (21473-05-2)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾;

DOI:10.1021/ja00528a056

Reference yield: 68.0%

6-phenyl-2-cyclohexen-1-ol (68099-17-2) → 1-phenylcyclohexa-2,4-diene (21473-05-2)

Guidance literature:

With 2,4-dinitrobenzenesulfenyl chloride; triethylamine; In 1,2-dichloro-ethane; for 2.5h; Heating;

DOI:10.1021/ja00389a028

upstream raw materials:

(1E,3Z)-hexa-1,3,5-trien-1-ylbenzene

6-phenyl-2-cyclohexen-1-ol

(1S,6R)-2-Acetoxy-6-phenyl-cyclohex-3-enecarboxylic acid

anthranilic acid

Downstream raw materials:

1-phenyl-cyclohexa-1,3-diene

(1R,4R,7S)-7-phenyl-3-(pyridin-2-yl)-2-oxa-3-azabicyclo[2.2.2]oct-5-ene

(1S,4S,8R)-8-phenyl-3-(pyridin-2-yl)-2-oxa-3-azabicyclo[2.2.2]oct-5-ene

tricarbonyl(η4-2-phenylcyclohexa-1,3-diene)iron