Cyclohexane, 1-ethenyl-1-methyl-

Base Information

• Chemical Name: Cyclohexane, 1-ethenyl-1-methyl-
• CAS No.: 21623-78-9
• Molecular Formula: C9H16
• Molecular Weight: 124.226
• Mol file: 21623-78-9.mol

Synonyms:

Chemical Property of Cyclohexane, 1-ethenyl-1-methyl-

Chemical Property:

• Boiling Point: 80 °C(Press: 95 Torr)
• Density: 0.8140 g/cm3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclohexane, 1-ethenyl-1-methyl-

There total 14 articles about Cyclohexane, 1-ethenyl-1-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

Dimethyl-phenyl-spiro[2.5]oct-1-ylmethyl-silane (141543-33-1) → 1-methyl-1-vinylcyclohexane (21623-78-9)

Guidance literature:

With boron trifluoride diacetate; In chloroform; at 0 ℃; for 0.0333333h;

DOI:10.1055/s-1992-34186

Reference yield:

C16H22N2O2S (30451-82-2) → 1-methyl-1-vinylcyclohexane (21623-78-9)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran;

DOI:10.1021/ja00728a029

Reference yield:

1-pyrrolidin-1-yl-1-vinylcyclohexane (14228-29-6) + 2-methyl-1,3,2-dioxaborolane (37003-57-9) → 1-methyl-1-vinylcyclohexane (21623-78-9) + n-propylidenecyclohexane (2129-93-3)

Guidance literature:

With triethylaluminum; triphenylphosphine; bis(acetylacetonate)nickel(II); In toluene; at 110 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1039/P19950002083

upstream raw materials:

2-(1-methylcyclohexyl)ethanol

C₁₆H₂₂N₂O₂S

1-methylcyclohexanecarbaldehyde

methyltriphenylphosphorane

Downstream raw materials:

Tetrachloro-1,1,1,3-(methyl-1'-cyclohexyl)-3-propan

Trichloro-1,1,1-(methyl-1'-cyclohexyl)-3-propan

Cyano-2-(methyl-1'-cyclohexyl)-4-buttersaeure-aethylester

Carboaethoxy-2-(methyl-1'-cyclohexyl)-4-buttersaeure-aethylester

Refernces

• 1、 Fleming,Sanderson,Terrett. "The regiochemistry of the protodesilylation of some cyclopropylmethylsilanes derived from allylsilanes". . p. 69 - 74. Retrieved 2007/10/02.