dicarbonyl(4-6-η,1-σ-cyclooctenediyl)triphenylphosphineruthenium

Base Information

• Chemical Name: dicarbonyl(4-6-η,1-σ-cyclooctenediyl)triphenylphosphineruthenium
• CAS No.: 55763-66-1
• Molecular Formula: C₂₈H₂₇O₂PRu
• Molecular Weight: 527.565
• Mol file: 55763-66-1.mol

Synonyms:

Chemical Property of dicarbonyl(4-6-η,1-σ-cyclooctenediyl)triphenylphosphineruthenium

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of dicarbonyl(4-6-η,1-σ-cyclooctenediyl)triphenylphosphineruthenium

There total 1 articles about dicarbonyl(4-6-η,1-σ-cyclooctenediyl)triphenylphosphineruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium tetrahydroborate (16940-66-2) + dicarbonyl(1-3:5,6-η-cyclooctadienylium)triphenylphosphineruthenium tetrafluoroborate → dicarbonyl(4-6-η,1-σ-cyclooctenediyl)triphenylphosphineruthenium (55763-66-1)

Guidance literature:

In water; under Ar, soln. of Ru complex in water treated with soln. of stoich. amt. of NaBH4 in min. of water; extn. with Et2O, drying over MgSO4, evapn. in vac.;

DOI:10.1016/0022-328X(83)80201-0

Reference yield:

dicarbonyl(4-6-η,1-σ-cyclooctenediyl)triphenylphosphineruthenium (55763-66-1) + trityl tetrafluoroborate (341-02-6) → dicarbonyl(1-3:5,6-η-cyclooctadienylium)triphenylphosphineruthenium tetrafluoroborate

Guidance literature:

In dichloromethane; mixt. of CH2Cl2 solns. of educts kept under Ar for 30 min; Et2O added, ppt. purified by dissolution in CH2Cl2 and re-pptn. with Et2O;

DOI:10.1016/0022-328X(83)80201-0

upstream raw materials:

sodium tetrahydroborate