(3S,6S)-6-ethenyl-2,2,6-trimethyloxan-3-ol

Base Information

Chemical Name:(3S,6S)-6-ethenyl-2,2,6-trimethyloxan-3-ol
CAS No.:22628-11-1
Molecular Formula:C₁₀H₁₈O₂
Molecular Weight:170.252
Hs Code.:
UNII:P6B6JD2N2Z,7NT66SL1W9
DSSTox Substance ID:DTXSID101017552
Nikkaji Number:J405.691D
Wikidata:Q104923630
Metabolomics Workbench ID:44879
Mol file:22628-11-1.mol

Synonyms:Linalool oxide III;cis-Pyran linalool oxide;UNII-P6B6JD2N2Z;cis-Pyranoid linalool oxide;Linalool oxide pyranoid, cis-(-)-;P6B6JD2N2Z;FEMA No. 4593, cis-(-)-;(3S,6S)-6-ethenyl-2,2,6-trimethyloxan-3-ol;14009-71-3;UNII-7NT66SL1W9;FEMA No. 4593, cis-(+/-)-;7NT66SL1W9;2H-Pyran-3-ol, 6-ethenyltetrahydro-2,2,6-trimethyl-, (3S,6S)-;2H-Pyran-3-ol, 6-ethenyltetrahydro-2,2,6-trimethyl-, (3S-cis)-;PYRANOID LINALOOL OXIDE, CIS;22628-11-1;Linalool oxide pyranoid, cis-(+/-)-;Linalool oxide D;Linalool 3,7-oxide, cis-;(Z)-Pyranoid linalool oxide;cis-Linalool oxide (pyranoid);Pyranoid linalool oxide, cis-;(3S,6S)-Pyranol;cis-Linalool oxide pyran;cis-6-ethenyltetrahydro-2,2,6-trimethylpyran-3-ol;cis-2,6,6-Trimethyl-2-vinyl-5-hydroxytetrahydropyran;linalool oxide, cis-pyranoid;(3R,6R)-2,2,6-Trimethyl-6-vinyltetrahydro-2H-pyran-3-ol;BCTBAGTXFYWYMW-WCBMZHEXSA-N;CHEBI:180229;DTXSID101017552;LINALOOL OXIDE III (CIS, PYRANOID);(3s,6s)-2,2,6-trimethyl-6-vinyl-tetrahydro-pyran-3-ol;2H-PYRAN-3-OL, 6-ETHENYLTETRAHYDRO-2,2,6-TRIMETHYL-, CIS-;2H-PYRAN-3-OL, TETRAHYDRO-2,2,6-TRIMETHYL-6-VINYL-, CIS-;2H-PYRAN-3-OL, 6-ETHENYLTETRAHYDRO-2,2,6-TRIMETHYL-, (3R,6R)-REL-

Suppliers and Price of (3S,6S)-6-ethenyl-2,2,6-trimethyloxan-3-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of (3S,6S)-6-ethenyl-2,2,6-trimethyloxan-3-ol

Chemical Property:

XLogP3:1.4
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:170.130679813
Heavy Atom Count:12
Complexity:186

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(C(CCC(O1)(C)C=C)O)C
Isomeric SMILES:C[C@]1(CC[C@@H](C(O1)(C)C)O)C=C

Technology Process of (3S,6S)-6-ethenyl-2,2,6-trimethyloxan-3-ol

There total 5 articles about (3S,6S)-6-ethenyl-2,2,6-trimethyloxan-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: Acetic acid (R)-2,2,6-trimethyl-6-vinyl-tetrahydro-pyran-3-yl ester

: 10448-31-4,14009-71-3,14049-11-7,22628-11-1,24048-52-0,39028-58-5,41720-62-1
2,2,6-trimethyl-6-vinyltetrahydropyran-3-ol

Guidance literature:: With sodium hydroxide; In methanol; for 12h; Ambient temperature;
DOI:10.1016/0040-4020(95)00084-L

Reference yield:

: 126-91-0
linalool

: 10448-31-4,14009-71-3,14049-11-7,22628-11-1,24048-52-0,39028-58-5,41720-62-1
2,2,6-trimethyl-6-vinyltetrahydropyran-3-ol

: 23007-29-6,37267-80-4
cis-5-ethenyltetrahydro-α,α,5-trimethyl-2-furan methanol

: 41720-55-2,37267-80-4
2-((5R)-tetrahydro-5-methyl-5-vinylfuran-2-yl)propan-2-ol

: 2-(1-hydroxy-1-methylethyl)-5-methyl-5-(oxiran-2-yl)tetrahydrofuran

Guidance literature:: With tert.-butylhydroperoxide; vanadium(V)((1R,2S)-aminoindanol-derived) catalyst; In chloroform; at 25 ℃; for 12h;
DOI:10.1055/s-2003-36793

Reference yield:

: 126-90-9
(S)-(+)-linalool

: 10448-31-4,14009-71-3,14049-11-7,22628-11-1,24048-52-0,39028-58-5,41720-62-1
2,2,6-trimethyl-6-vinyltetrahydropyran-3-ol

: 286428-24-8,37267-80-4
(R)-linalyl oxide

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; trichloroacetic acid; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) CH₂Cl₂, 0 deg C, 2 h; 2.) ether, r.t., 12 h;
DOI:10.1016/0040-4020(95)00084-L