cis-{RuI₂(CO)2(C₁₈H₁₅As)2}

Base Information

• Chemical Name: cis-{RuI₂(CO)2(C₁₈H₁₅As)2}
• CAS No.: 60660-62-0
• Molecular Formula: C₃₈H₃₀As₂I₂O₂Ru
• Molecular Weight: 1023.38
• Mol file: 60660-62-0.mol

Synonyms:

Chemical Property of cis-{RuI₂(CO)2(C₁₈H₁₅As)2}

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-{RuI₂(CO)2(C₁₈H₁₅As)2}

There total 2 articles about cis-{RuI₂(CO)2(C₁₈H₁₅As)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

all-trans-[Ru(CO)2(AsPh3)I2] * THF → cis-{RuI2(CO)2(C18H15As)2} (60660-62-0)

Guidance literature:

In not given; N2-atmosphere; in CHCl3 or C6H5Cl (not specified), absence of light, heating;

DOI:10.1039/DT9760000953

Reference yield:

C(x)I(x)O(x)Ru(x) + triphenyl-arsane (603-32-7) → cis-{RuI2(CO)2(C18H15As)2} (60660-62-0)

Guidance literature:

In ethanol; formation from (RuI2(CO)2)n and an alcoholic soln. of triphenylarsine on heating in a sealing tube at 120°C for 12 h;; extraction of the raw product with benzene; addn. of ether; washing the ppt. with ether;;

DOI:10.1016/0022-1902(57)80063-3

Reference yield:

cis-{RuI2(CO)2(C18H15As)2} (60660-62-0) → all-trans-[Ru(CO)2(AsPh3)I2] * THF

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); N2-atmosphere; Pyrex vessel, 125-W Hg lamp, cooling with air (crystn.); elem. anal.;

DOI:10.1039/DT9760000953

upstream raw materials:

triphenyl-arsane