4-{(E)-[4-(Diethylamino)phenyl]diazenyl}benzonitrile

Base Information

Chemical Name:4-{(E)-[4-(Diethylamino)phenyl]diazenyl}benzonitrile
CAS No.:22700-64-7
Molecular Formula:C17H18N4
Molecular Weight:278.357
Hs Code.:
DSSTox Substance ID:DTXSID20548898
Nikkaji Number:J407.655I
Mol file:22700-64-7.mol

Synonyms:22700-64-7;4-{(E)-[4-(Diethylamino)phenyl]diazenyl}benzonitrile;SCHEMBL6716916;DTXSID20548898

Suppliers and Price of 4-{(E)-[4-(Diethylamino)phenyl]diazenyl}benzonitrile

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-{(E)-[4-(Diethylamino)phenyl]diazenyl}benzonitrile

Chemical Property:

XLogP3:4.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:278.153146591
Heavy Atom Count:21
Complexity:364

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCN(CC)C1=CC=C(C=C1)N=NC2=CC=C(C=C2)C#N

Technology Process of 4-{(E)-[4-(Diethylamino)phenyl]diazenyl}benzonitrile

There total 1 articles about 4-{(E)-[4-(Diethylamino)phenyl]diazenyl}benzonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 91-66-7
N,N-diethylaniline

: 873-74-5
4-Aminobenzonitrile

: 22700-64-7
4-(p-diethylaminophenylazo)benzonitrile

Guidance literature:: 4-Aminobenzonitrile; With hydrogenchloride; sodium nitrite; at 0 - 5 ℃; for 2h;

N,N-diethylaniline; In tetrahydrofuran; hydrogenchloride; for 1h;
DOI:10.1039/b300777d

Reference yield: 84.0%

: 22700-64-7
4-(p-diethylaminophenylazo)benzonitrile

: 34295-56-2
4-(p-diethylaminophenylazo)benzaldehyde

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 3h;
DOI:10.1039/b300777d

Reference yield:

: 22700-64-7
4-(p-diethylaminophenylazo)benzonitrile

: 4-[4-(p-diethylaminophenylazo)styryl]benzonitrile

Guidance literature:: Multi-step reaction with 2 steps

1.1: 84 percent / DIBAL-H / hexane; tetrahydrofuran / 3 h / -78 - 20 °C

2.1: LDA / tetrahydrofuran / 0.5 h / -78 °C

2.2: 92 percent / tetrahydrofuran / 24 h / 20 °C

With diisobutylaluminium hydride; lithium diisopropyl amide; In tetrahydrofuran; hexane; 2.2: Horner-Wittig reaction;
DOI:10.1039/b300777d