Lithiomethyl phenyl selenide

Base Information

• Chemical Name: Lithiomethyl phenyl selenide
• CAS No.: 22859-62-7
• Molecular Formula: C7H7LiSe
• Molecular Weight: 177.034
• DSSTox Substance ID: DTXSID30456536
• Mol file: 22859-62-7.mol

Synonyms:lithiomethyl phenyl selenide;22859-62-7;AGN-PC-0NGI2A;DTXSID30456536

Chemical Property of Lithiomethyl phenyl selenide

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 177.98730
• Heavy Atom Count: 9
• Complexity: 59.9

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: [Li+].[CH2-][Se]C1=CC=CC=C1

Technology Process of Lithiomethyl phenyl selenide

There total 1 articles about Lithiomethyl phenyl selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(phenylseleno)methane (20343-90-2) → lithio-phenylselenyl-methane (22859-62-7)

Guidance literature:

With tert.-butyl lithium; In tetrahydrofuran;

DOI:10.1524/zpch.2001.215.1.077

Reference yield: 75.0%

2-hexyl-2-methyloxirane (6924-86-3) + lithio-phenylselenyl-methane (22859-62-7) → 3-Methyl-1-phenylselanyl-nonan-3-ol (74581-39-8)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; In tetrahydrofuran; at -78 - 20 ℃;

DOI:10.1016/S0040-4039(01)85563-5

Reference yield: 73.0%

lithio-phenylselenyl-methane (22859-62-7) + (4S,5R)-5-((1E,3E)-1,3,6,6-tetramethyl-1,3-hexadienyl)-4-methyl-2-pentene-5-olide (218778-69-9) → (3R,4S,5R)-5-((1E,3E)-1,3,6,6-tetramethyl-1,3-hexadienyl)-4-methyl-3-(phenylseleno)methyl-5-pentenolide (218778-72-4)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; In tetrahydrofuran;

DOI:10.1021/jo981744m

upstream raw materials:

bis(phenylseleno)methane

Downstream raw materials:

1-tert-butyl-4-methylenecyclohexane

3-Methyl-1-phenylselanyl-nonan-3-ol

Decyl phenyl selenide

phenyl undecyl selenide