(4R)-4-methylhept-1-ene

Base Information

• Chemical Name: (4R)-4-methylhept-1-ene
• CAS No.: 13151-05-8
• Molecular Formula: C8H16
• Molecular Weight: 112.215
• Hs Code.: 2901299090
• DSSTox Substance ID: DTXSID401015850
• Mol file: 13151-05-8.mol

Synonyms:DTXSID401015850

Chemical Property of (4R)-4-methylhept-1-ene

Chemical Property:

• Vapor Pressure: 25.7mmHg at 25°C
• Melting Point: -103.01°C (estimate)
• Refractive Index: 1.4080
• Boiling Point: 112.4°Cat760mmHg
• Flash Point: 15.5°C
• PSA: 0.00000
• Density: 0.719g/cm³
• LogP: 2.99870
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 112.125200510
• Heavy Atom Count: 8
• Complexity: 55.1

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC(C)CC=C
• Isomeric SMILES: CCC[C@@H](C)CC=C

Technology Process of (4R)-4-methylhept-1-ene

There total 4 articles about (4R)-4-methylhept-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

7-iodo-4-methyl-hept-1-ene → 4-methyl-1-heptene (13151-05-8) + 1,3-dimethylcyclohexane (638-04-0,2207-03-6,69685-67-2,69685-68-3,129939-72-6,129939-73-7,591-21-9) + methylcycloheptane (4126-78-7)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane; In benzene; Heating;

DOI:10.1021/ol0160755

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → 2,4-dimethyl-1-pentene (2213-32-3) + 4-Methyl-1-pentene (691-37-2,25068-26-2) + 4-methyl-1-heptene (13151-05-8) + isobutene (115-11-7,15220-85-6)

Guidance literature:

With MAO; (η⁵-C5Me5)2HfCl2; In hexane; benzene; at 50 ℃; for 0.5h; under 1500.15 Torr; Further Variations:; Catalysts; Reagents; Kinetics; Product distribution;

DOI:10.1021/ja063717g

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → 2-Methyl-1-pentene (763-29-1) + 2,4-dimethyl-1-pentene (2213-32-3) + 4,6-dimethylhept-1-ene (7379-69-3) + 4-Methyl-1-pentene (691-37-2,25068-26-2) + 1-penten (109-67-1) + 4-methyl-1-heptene (13151-05-8)

Guidance literature:

bis(pentamethylcyclopentadienyl)zirconium(IV) dichloride; tetramethyldialuminoxane; In benzene; at 50 ℃; for 2h; Product distribution; other catalysts;

DOI:10.1246/cl.1991.1525

upstream raw materials:

β-oxy-δ-methyl-heptane

propene

Refernces

• 1、 Bailey, William F.,Longstaff, Sarah C.. "Cyclization of methyl-substituted 6-heptenyl radicals". . p. 2217 - 2219. Retrieved 2007/10/03.