1,10-Phenanthroline, 4,7-bis[[4-[[5-(1,1-dimethylethyl)-3-iodo-2-methoxyphenyl]ethynyl]phenyl] ethynyl]-3,8-dihexyl-

Base Information

Chemical Name:1,10-Phenanthroline, 4,7-bis[[4-[[5-(1,1-dimethylethyl)-3-iodo-2-methoxyphenyl]ethynyl]phenyl] ethynyl]-3,8-dihexyl-
CAS No.:233262-47-0
Molecular Formula:C66H66I2N2O2
Molecular Weight:1173.07
Hs Code.:
Mol file:233262-47-0.mol

Synonyms:

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Chemical Property of 1,10-Phenanthroline, 4,7-bis[[4-[[5-(1,1-dimethylethyl)-3-iodo-2-methoxyphenyl]ethynyl]phenyl] ethynyl]-3,8-dihexyl-

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Technology Process of 1,10-Phenanthroline, 4,7-bis[[4-[[5-(1,1-dimethylethyl)-3-iodo-2-methoxyphenyl]ethynyl]phenyl] ethynyl]-3,8-dihexyl-

There total 10 articles about 1,10-Phenanthroline, 4,7-bis[[4-[[5-(1,1-dimethylethyl)-3-iodo-2-methoxyphenyl]ethynyl]phenyl] ethynyl]-3,8-dihexyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 127799-20-6
5-(tert-butyl)-1,3-diiodo-2-methoxybenzene

: 233262-46-9
4,7-bis-(4-ethynylphenylethynyl)-3,8-dihexyl-1,10-phenanthroline

: 233262-47-0
4,7-bis-[4-(5-tert-butyl-3-iodo-2-methoxyphenylethynyl)phenylethynyl]-3,8-dihexyl-1,10-phenanthroline

Guidance literature:: With triethylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In benzene; for 72h; Heating;
DOI:10.1002/chem.200305770

Reference yield:

: 175345-90-1
1-((triisopropylsilyl)ethynyl)-4-ethynylbenzene

: 233262-47-0
4,7-bis-[4-(5-tert-butyl-3-iodo-2-methoxyphenylethynyl)phenylethynyl]-3,8-dihexyl-1,10-phenanthroline

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / CuI; triethylamine / [PdCl₂(PPh₃)2] / benzene / 72 h / Heating

2: 92 percent / tetrabutylammonium fluoride trihydrate / tetrahydrofuran / 0.5 h / 20 °C

3: 88 percent / triethylamine / [Pd(PPh₃)4] / benzene / 72 h / Heating

With copper(l) iodide; tetrabutyl ammonium fluoride; triethylamine; bis-triphenylphosphine-palladium(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; benzene; 1: Sonogashira coupling / 3: Sonogashira coupling;
DOI:10.1002/chem.200305770

Reference yield:

: 233262-45-8
3,8-dihexyl-4,7-bis-{4-[(trisisopropylsilyl)ethynyl]phenylethynyl}-1,10-phenanthroline

: 233262-47-0
4,7-bis-[4-(5-tert-butyl-3-iodo-2-methoxyphenylethynyl)phenylethynyl]-3,8-dihexyl-1,10-phenanthroline

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / tetrabutylammonium fluoride trihydrate / tetrahydrofuran / 0.5 h / 20 °C

2: 88 percent / triethylamine / [Pd(PPh₃)4] / benzene / 72 h / Heating

With tetrabutyl ammonium fluoride; triethylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; benzene; 2: Sonogashira coupling;
DOI:10.1002/chem.200305770