4-Stilbene carboxaldehyde

Base Information

• Chemical Name: 4-Stilbene carboxaldehyde
• CAS No.: 32555-96-7
• Molecular Formula: C15H12 O
• Molecular Weight: 208.26
• Hs Code.: 2912299000
• European Community (EC) Number: 622-987-2,672-707-8
• Nikkaji Number: J1.321.482D,J236.258I
• Mol file: 32555-96-7.mol

Synonyms:4-Formyl-trans-stilbene;40200-69-9;4-Stilbene carboxaldehyde;(e)-4-styrylbenzaldehyde;trans-4-Stilbenecarboxaldehyde;4-[(E)-2-Phenylethenyl]benzaldehyde;32555-96-7;4-styryl-benzaldehyde;4-STILBENECARBOXALDEHYDE);Benzaldehyde,4-(2-phenylethenyl)-;Stilbene-4-carbaldehyde;Benzaldehyde, 4-[(1E)-2-phenylethenyl]-;trans-4-stilbenecarbaldehyde;(E)-Stilbene-4-carbaldehyde;SCHEMBL1616534;SCHEMBL2165005;MFCD00011580;trans-4-Stilbenecarboxaldehyde, 97%;AKOS015837475;4-[(1E)-2-phenylethenyl]benzaldehyde;4-[(E)-2-Phenylethenyl]benzaldehyde #;AS-58234;CS-0452160;F0412;D90670

Chemical Property of 4-Stilbene carboxaldehyde

Chemical Property:

• Vapor Pressure: 2E-05mmHg at 25°C
• Boiling Point: 361.9°Cat760mmHg
• Flash Point: 203.1°C
• PSA: 17.07000
• Density: 1.129g/cm³
• LogP: 3.66950
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 208.088815002
• Heavy Atom Count: 16
• Complexity: 230

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C=CC2=CC=C(C=C2)C=O
• Isomeric SMILES: C1=CC=C(C=C1)/C=C/C2=CC=C(C=C2)C=O

Technology Process of 4-Stilbene carboxaldehyde

There total 70 articles about 4-Stilbene carboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 4-bromo-benzaldehyde (1122-91-4) → 4-stilbenecarboxaldehyde (32555-96-7,40200-69-9)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 100 ℃; for 4h;

DOI:10.1016/j.tetlet.2011.05.006

Reference yield: 99.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 4-chlorobenzaldehyde (104-88-1) → 4-styrylbenzaldehyde (32555-96-7,40200-69-9)

Guidance literature:

With cesium acetate; PdCl[(C₆H₃)(OP(i-Pr)2)2-2,6]; In 1,4-dioxane; at 120 ℃; for 120h;

DOI:10.1039/b004412l

Reference yield: 98.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + p-(iodophenyl)carboxaldehyde (15164-44-0) → 4-styrylbenzaldehyde (32555-96-7,40200-69-9)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 3h; Inert atmosphere;

DOI:10.1007/s10562-021-03767-6

upstream raw materials:

Stilben-4-carbonsaeure-chlorid

benzyltriphenylphosphonium chloride

terephthalaldehyde,

styrene

Downstream raw materials:

2-phenyl-3ξ-(trans-stilben-4-yl)-acrylic acid

2,3ξ-di-trans-stilben-4-yl-acrylic acid

(+/-)-1-trans-stilben-4-yl-propan-1-ol

(+/-)-5-trans-stilben-4-yl-imidazolidine-2,4-dione

Refernces

• 1、 Aydemir, Murat,Durap, Feyyaz,Baysal, Akin. "New Pd(II) and Pt(II)-diaminophosphine complexes bearing cyclohexyl or isopropyl moiety: Use of Pd(II) complexes as precatalyst in Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions". . p. 1279 - 1288. Retrieved 2015.
• 2、 Karata?, Mert Olgun,?zdemir, Nam?k,Al?c?, Bülent,?zdemir, ?smail. "N-heterocyclic carbene palladium complexes with different N-coordinated ligands: Comparison of their catalytic activities in Suzuki-Miyaura and Mizoroki-Heck reactions". . . Retrieved 2020.
• 3、 Korkmaz, S. Aslan,Karadag,Korkmaz,Andac,Guerbuez,Oezdemir,Topkaya. "Five complexes containing N, N -bis(2-hydroxyethyl)-ethylenediamine with tetracyanidopalladate(II): Synthesis, crystal structures, thermal, magnetic, and catalytic properties". . p. 3072 - 3091. Retrieved 2013.
• 4、 Poyatos, Macarena,Marquez, Francisco,Peris, Eduardo,Claver, Carmen,Fernandez, Elena. "Preparation of a new clay-immobilized highly stable palladium catalyst and its efficient recyclability in the Heck reaction". . p. 425 - 431. Retrieved 2003.
• 5、 Fatahi, Yousef,Ghaempanah, Aram,Ma?mani, Leila,Mahdavi, Mohammad,Bahadorikhalili, Saeed. "Palladium supported aminobenzamide modified silica coated superparamagnetic iron oxide as an applicable nanocatalyst for Heck cross-coupling reaction". . . Retrieved 2021/01/26.
• 6、 Alavi G., Seyyedeh Ameneh,Nasseri, Mohammad Ali,Kazemnejadi, Milad,Allahresani, Ali,Hussainzadeh, Mahdi. "NiFe2O4@SiO2@ZrO2/SO42-/Cu/Co nanoparticles: A novel, efficient, magnetically recyclable and bimetallic catalyst for Pd-free Suzuki, Heck and C-N cross-coupling reactions in aqueous media". . p. 7741 - 7757. Retrieved 2021/05/13.