Benzene, 1-(1,1-dimethylethyl)-4-(1-methylpropyl)-

Base Information

• Chemical Name: Benzene, 1-(1,1-dimethylethyl)-4-(1-methylpropyl)-
• CAS No.: 25027-33-2
• Molecular Formula: C14H22
• Molecular Weight: 190.329
• Mol file: 25027-33-2.mol

Synonyms:Benzene,1-(1,1-dimethylethyl)-4-(1-methylpropyl);1-sec-butyl-4-tert-butyl-benzene;1-sec-Butyl-4-tert-butyl-benzol;p-(sec-Butyl)-tert-butylbenzol;4-[4-(Trifluoromethyl)phenyl]-4,5-dihydro-3H-isoxazolo[3,4,5-kl]acridine;4-tert-butyl-1-sec-butylbenzene;

Chemical Property of Benzene, 1-(1,1-dimethylethyl)-4-(1-methylpropyl)-

Chemical Property:

• PSA: 0.00000
• LogP: 4.49760

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, 1-(1,1-dimethylethyl)-4-(1-methylpropyl)-

There total 8 articles about Benzene, 1-(1,1-dimethylethyl)-4-(1-methylpropyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

4-(tert-butyl)chlorobenzene (3972-56-3) + sec.-butyllithium (598-30-1) → 1-(1,1-dimethylethyl)-4-(1-methylpropyl)benzene (25027-33-2)

Guidance literature:

4-(tert-butyl)chlorobenzene; With (x)C₁₇H₁₄O*2Pd; C₈₈H₁₃₄Cl₂P₄Pd₂; In toluene; for 0.5h; Schlenk technique; Inert atmosphere;

sec.-butyllithium; In toluene; at 22 ℃; for 1h; Schlenk technique; Inert atmosphere;

DOI:10.1002/anie.202008866

Reference yield: 76.0%

1-bromo-4-tert-butylbenzene (3972-65-4) + sec-butyl zinc chloride (74133-06-5) → 1-(1,1-dimethylethyl)-4-(1-methylpropyl)benzene (25027-33-2)

Guidance literature:

at 20 ℃;

DOI:10.1021/jo025732j

Reference yield: 42.7%

tert-butylbenzene (253185-03-4,253185-04-5) + s-butyl chloride (78-86-4,53178-20-4) → 1-(1,1-dimethylethyl)-4-(1-methylpropyl)benzene (25027-33-2)

Guidance literature:

With Perfluorooctanesulfonic acid; at 110 - 115 ℃; for 10h;

DOI:10.1080/00397919108021046

upstream raw materials:

2-methyl-propan-1-ol

sec-Butylbenzene

tert-butylbenzene

butan-1-ol

Downstream raw materials:

hexabromobenzene