IrCl(C₈H₁₂)(P(BrC₆F₄)(C₆H₅)2)

Base Information

• Chemical Name: IrCl(C₈H₁₂)(P(BrC₆F₄)(C₆H₅)2)
• CAS No.: 112443-92-2
• Molecular Formula: C₂₆H₂₂BrClF₄IrP
• Molecular Weight: 749.005
• Mol file: 112443-92-2.mol

Synonyms:

Chemical Property of IrCl(C₈H₁₂)(P(BrC₆F₄)(C₆H₅)2)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of IrCl(C₈H₁₂)(P(BrC₆F₄)(C₆H₅)2)

There total 1 articles about IrCl(C₈H₁₂)(P(BrC₆F₄)(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro(1,5-cyclooctadiene)iridium(I) dimer + (2-bromo-3,4,5,6-tetrafluorophenyl)diphenylphosphine (27384-33-4) → IrCl(C8H12)(P(BrC6F4)(C6H5)2) (112443-92-2)

Guidance literature:

In chloroform; reaction at room temp. with stoichiometric amts.;

Reference yield: 20.0%

{IrCl(cis-1,5-cyclooctadiene)(P(o-BrC6F4)Ph2)} (112443-92-2) + (2-bromo-3,4,5,6-tetrafluorophenyl)diphenylphosphine (27384-33-4) → {IrBr2(P(C6F4)Ph2)(P(o-BrC6F4)Ph2)} + {IrCl2(P(C6F4)Ph2)(P(o-BrC6F4)Ph2)} + {IrBrCl(P(C6F4)Ph2)(P(o-BrC6F4)Ph2)}

Guidance literature:

In xylene; under N2 or Ar, refluxed for 10 h; evapd. to dryness, dissolved in CH2Cl2, column chromy. on silica-gel in hexane: CH2Cl2/hexane 1:1 - dibromo- and bromochloro-compd., CH2Cl2 - dichloro-compd., all fractions evapd. to dryness, recrystn. (CH2Cl2-hexane); observed by TLC and (31)P-NMR;

DOI:10.1016/S0277-5387(00)80453-2

Reference yield:

IrCl(C8H12)(P(BrC6F4)(C6H5)2) (112443-92-2) + (2-bromo-3,4,5,6-tetrafluorophenyl)diphenylphosphine (27384-33-4) → IrCl(CO)(P(BrC6F4)(C6H5)2)2 (112461-98-0)

Guidance literature:

With CO; In chloroform; reaction of equimolar amts. in CHCl3 with CO (1 atm pressure);

upstream raw materials:

(2-bromo-3,4,5,6-tetrafluorophenyl)diphenylphosphine

Downstream raw materials:

IrCl(CO)(P(BrC₆F₄)(C₆H₅)2)2