8-Tridecen-1-ol, 5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,13-bis[(4-methoxyphenyl )methoxy]-2,4,6,8,10,12-hexamethyl-, (2S,3S,4R,5R,6S,8Z,10S,11R,12S)-

Base Information

Chemical Name:8-Tridecen-1-ol, 5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,13-bis[(4-methoxyphenyl )methoxy]-2,4,6,8,10,12-hexamethyl-, (2S,3S,4R,5R,6S,8Z,10S,11R,12S)-
CAS No.:256920-79-3
Molecular Formula:C47H82O7Si2
Molecular Weight:815.335
Hs Code.:
Mol file:256920-79-3.mol

8-Tridecen-1-ol,
5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,13-bis[(4-methoxyphenyl
)methoxy]-2,4,6,8,10,12-hexamethyl-,
(2S,3S,4R,5R,6S,8Z,10S,11R,12S)-

Synonyms:

Suppliers and Price of 8-Tridecen-1-ol, 5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,13-bis[(4-methoxyphenyl )methoxy]-2,4,6,8,10,12-hexamethyl-, (2S,3S,4R,5R,6S,8Z,10S,11R,12S)-

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Chemical Property of 8-Tridecen-1-ol, 5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,13-bis[(4-methoxyphenyl )methoxy]-2,4,6,8,10,12-hexamethyl-, (2S,3S,4R,5R,6S,8Z,10S,11R,12S)-

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Technology Process of 8-Tridecen-1-ol, 5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,13-bis[(4-methoxyphenyl )methoxy]-2,4,6,8,10,12-hexamethyl-, (2S,3S,4R,5R,6S,8Z,10S,11R,12S)-

There total 3 articles about 8-Tridecen-1-ol, 5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,13-bis[(4-methoxyphenyl )methoxy]-2,4,6,8,10,12-hexamethyl-, (2S,3S,4R,5R,6S,8Z,10S,11R,12S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: (4S,5S)-4-[(Z)-(1R,2R,3S,7S,8R,9S)-2,8-bis(tert-butyldimethylsilanyloxy)-10-(4-methoxybenzyloxy)-1,3,5,7,9-pentamethyldec-5-enyl]-2-(4-methoxyphenyl)-5-methyl-[1,3]dioxane

: 256920-79-3
(Z)-(2S,3S,4R,5R,6S,10S,11R,12S)-5,11-bis(tert-butyldimethylsilanyloxy)-3,13-bis(4-methoxybenzyloxy)-2,4,6,8,10,12-hexamethyltridec-8-en-1-ol

Guidance literature:: With diisobutylaluminium hydride; In toluene; at -20 - 5 ℃; for 2h; Large scale;
DOI:10.1021/op034133r

Reference yield:

: C₃₂H₅₅BO₄Si

: 256920-79-3
(Z)-(2S,3S,4R,5R,6S,10S,11R,12S)-5,11-bis(tert-butyldimethylsilanyloxy)-3,13-bis(4-methoxybenzyloxy)-2,4,6,8,10,12-hexamethyltridec-8-en-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate / N,N-dimethyl-formamide / 22.5 h / 25 °C / Large scale

2: diisobutylaluminium hydride / toluene / 2 h / -20 - 5 °C / Large scale

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; diisobutylaluminium hydride; caesium carbonate; In N,N-dimethyl-formamide; toluene; 1: |Suzuki Coupling;
DOI:10.1021/op034133r

Reference yield:

: 398518-61-1
tert-butyl-((1S,2R)-3-iodo-1-{(R)-1-[(4S,5S)-2-(4-methoxyphenyl)-5-methyl-[1,3]dioxin-4-yl]-ethyl}-2-methylpropoxy)dimethylsilane

: 256920-79-3
(Z)-(2S,3S,4R,5R,6S,10S,11R,12S)-5,11-bis(tert-butyldimethylsilanyloxy)-3,13-bis(4-methoxybenzyloxy)-2,4,6,8,10,12-hexamethyltridec-8-en-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1.1: tert.-butyl lithium / diethyl ether; hexane; tetrahydrofuran / 0.5 h / -80 - -78 °C

1.2: 0.25 h / -80 - -78 °C

2.1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate / N,N-dimethyl-formamide / 22.5 h / 25 °C / Large scale

3.1: diisobutylaluminium hydride / toluene / 2 h / -20 - 5 °C / Large scale

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; tert.-butyl lithium; diisobutylaluminium hydride; caesium carbonate; In tetrahydrofuran; diethyl ether; hexane; N,N-dimethyl-formamide; toluene; 2.1: |Suzuki Coupling;
DOI:10.1021/op034133r