Cyclopentanol, 2,3-bis(phenylmethoxy)-4-[(phenylmethoxy)methyl]-, (1S,2R,3R,4R)-

Base Information

Chemical Name:Cyclopentanol, 2,3-bis(phenylmethoxy)-4-[(phenylmethoxy)methyl]-, (1S,2R,3R,4R)-
CAS No.:257603-85-3
Molecular Formula:C27H30O4
Molecular Weight:418.533
Hs Code.:
Mol file:257603-85-3.mol

Synonyms:

Suppliers and Price of Cyclopentanol, 2,3-bis(phenylmethoxy)-4-[(phenylmethoxy)methyl]-, (1S,2R,3R,4R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Cyclopentanol, 2,3-bis(phenylmethoxy)-4-[(phenylmethoxy)methyl]-, (1S,2R,3R,4R)-

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Cyclopentanol, 2,3-bis(phenylmethoxy)-4-[(phenylmethoxy)methyl]-, (1S,2R,3R,4R)-

There total 8 articles about Cyclopentanol, 2,3-bis(phenylmethoxy)-4-[(phenylmethoxy)methyl]-, (1S,2R,3R,4R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 257603-84-2
2,3,5-tri-O-benzyl-4a-carba-β-D-arabinofuranose

: 257603-85-3
2,3,5-tri-O-benzyl-4a-carba-α-D-arabinofuranose

Guidance literature:: 2,3,5-tri-O-benzyl-4a-carba-β-D-arabinofuranose; With triphenylphosphine; diethylazodicarboxylate; 4-nitro-benzoic acid; In toluene; at 20 ℃; for 4h;

With sodium methylate; In methanol; at 20 ℃; for 0.5h; Further stages.;
DOI:10.1021/jo010827r

Reference yield:

: 257603-80-8
1,3,4-tri-O-benzyl-6,7-didehydro-6,7-dideoxy-5-O-methoxymethyl-L-arabino-hept-2-ulose

: 257603-85-3
2,3,5-tri-O-benzyl-4a-carba-α-D-arabinofuranose

Guidance literature:: Multi-step reaction with 5 steps

1.1: 77 percent / tetrahydrofuran / 3 h / -78 - 20 °C

2.1: 78 percent / (1,3-Mes-imidazolidin-2-yl)-(PhC=)RuCl₂PCy₃ / toluene / 2.5 h / 60 °C

3.1: 88 percent / H₂ / (Ph₃P)3RhCl / CH₂Cl₂ / 6 h / 20 °C

4.1: 95 percent / conc. HCl / methanol / 6 h / 20 °C

5.1: p-nitrobenzoic acid; Ph₃P; DEAD / toluene / 4 h / 20 °C

5.2: 84 percent / NaOMe / methanol / 0.5 h / 20 °C

With hydrogenchloride; hydrogen; triphenylphosphine; diethylazodicarboxylate; 4-nitro-benzoic acid; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; Wilkinson's catalyst; In tetrahydrofuran; methanol; dichloromethane; toluene;
DOI:10.1021/jo010827r

Reference yield:

: 257603-79-5
4,5,7-tri-O-benzyl-1,2-didehydro-1,2-dideoxy-3-O-methoxymethyl-D-manno-heptitol

: 257603-85-3
2,3,5-tri-O-benzyl-4a-carba-α-D-arabinofuranose

Guidance literature:: Multi-step reaction with 6 steps

1.1: 93 percent / PCC; NaOAc; 4 Angstroem molecular sieves / CH₂Cl₂ / 2 h / 20 °C

2.1: 77 percent / tetrahydrofuran / 3 h / -78 - 20 °C

3.1: 78 percent / (1,3-Mes-imidazolidin-2-yl)-(PhC=)RuCl₂PCy₃ / toluene / 2.5 h / 60 °C

4.1: 88 percent / H₂ / (Ph₃P)3RhCl / CH₂Cl₂ / 6 h / 20 °C

5.1: 95 percent / conc. HCl / methanol / 6 h / 20 °C

6.1: p-nitrobenzoic acid; Ph₃P; DEAD / toluene / 4 h / 20 °C

6.2: 84 percent / NaOMe / methanol / 0.5 h / 20 °C

With hydrogenchloride; 4 A molecular sieve; hydrogen; sodium acetate; triphenylphosphine; pyridinium chlorochromate; diethylazodicarboxylate; 4-nitro-benzoic acid; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; Wilkinson's catalyst; In tetrahydrofuran; methanol; dichloromethane; toluene;
DOI:10.1021/jo010827r