Rhodium, (carbonothioyl)chlorobis(triphenylphosphine)-

Base Information

Chemical Name:Rhodium, (carbonothioyl)chlorobis(triphenylphosphine)-
CAS No.:26500-10-7
Molecular Formula:C₃₇H₃₀ClP₂RhS
Molecular Weight:707.017
Hs Code.:

Synonyms:

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Chemical Property of Rhodium, (carbonothioyl)chlorobis(triphenylphosphine)-

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Technology Process of Rhodium, (carbonothioyl)chlorobis(triphenylphosphine)-

There total 10 articles about Rhodium, (carbonothioyl)chlorobis(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 14694-95-2
Wilkinson's catalyst

: 59349-68-7,26500-10-7
{RhCl(CS)(PPh₃)2}

Guidance literature:: With carbon disulfide; triphenylphosphine; In benzene; (N2); to soln. of Rh complex was added excess CS2 and PPh3, mixt. was refluxed for 1 h; soln. was treated with hexane, formed ppt. was filtered off, washed with EtOH and Et2O and dried in vac.; elem. anal.;
DOI:10.1016/S0022-328X(00)82814-4

Reference yield: 42.8%

: 14694-95-2
Wilkinson's catalyst

: [(π-C5H5)Fe(CO)2(CS)]PF6

: 15318-33-9,16353-77-8,13938-94-8
trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I)

: 59349-68-7,26500-10-7
{RhCl(CS)(PPh₃)2}

: 61113-61-9
[(π-C5H5)Fe(CO)(CS)(P(C6H5)3)]PF6

Guidance literature:: In acetonitrile; N2-atmosphere; equimolar amts., stirring (2 h); solvent removal (reduced pressure), chromy. (alumina);
DOI:10.1016/S0020-1693(00)94702-9

Reference yield: 30.0%

: 14694-95-2
Wilkinson's catalyst

: 59349-68-7,26500-10-7
{RhCl(CS)(PPh₃)2}

: Rh⁽³⁺⁾*Cl^(1-)*CS₃^(2-)*3P(C₆H₅)3=RhCl(CS₃)(P(C₆H₅)3)3

Guidance literature:: With carbon disulfide; In benzene; (N2); to soln. of Rh complex was added excess CS2 and mixt. was refluxed for 2 h; mixt. was sepd. by chromy. (silica gel); intermediates were not isolated, detected by IR; RhClCS-complex was eluted by hexane/CH2Cl2 and pptd. with hexane; elem. anal.; RhCS3-complex was not isolated, detected by IRafter chromy.;
DOI:10.1016/S0022-328X(00)82814-4