Benzenamine, 2-methyl-N-sulfinyl-

Base Information

• Chemical Name: Benzenamine, 2-methyl-N-sulfinyl-
• CAS No.: 15182-74-8
• Molecular Formula: C₇H₇NOS
• Molecular Weight: 153.205
• DSSTox Substance ID: DTXSID10164884
• Nikkaji Number: J100.094B
• Wikidata: Q83033972
• Mol file: 15182-74-8.mol

Synonyms:1-methyl-2-(sulfinylamino)benzene;15182-74-8;Benzenamine, 2-methyl-N-sulfinyl-;o-Toluidine, N-sulfinyl-;N-Sulfinyl-o-toluidine;2-Methyl-N-sulfinylaniline;N-sulfinyltoluidine;o-Tolylsulfinylamine;Thionyl-o-toluidine;2-Methyl-N-sulfinylbenzenamine;SCHEMBL7294187;DTXSID10164884;MFCD26792662;AKOS017259208;LS-09079;2-methyl-N-(oxo-|E?-sulfanylidene)aniline;2-METHYL-N-(OXO-??-SULFANYLIDENE)ANILINE

Chemical Property of Benzenamine, 2-methyl-N-sulfinyl-

Chemical Property:

• Vapor Pressure: 0.0841mmHg at 25°C
• Boiling Point: 233.7°C at 760 mmHg
• Flash Point: 95.1°C
• PSA: 61.52000
• Density: 1.15g/cm³
• LogP: 2.88880
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 153.02483502
• Heavy Atom Count: 10
• Complexity: 154

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=CC=C1N=S=O

Technology Process of Benzenamine, 2-methyl-N-sulfinyl-

There total 3 articles about Benzenamine, 2-methyl-N-sulfinyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

o-toluidine (95-53-4) → 2-Methylsulfinylanilin (15182-74-8,52866-99-6)

Guidance literature:

With thionyl chloride; benzene;

Reference yield:

thionyl chloride (7719-09-7) + o-toluidine (95-53-4) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 2-Methylsulfinylanilin (15182-74-8,52866-99-6)

Guidance literature:

DOI:10.1111/j.1754-7121.2002.tb01858.x

Reference yield:

→ 2-Methylsulfinylanilin (15182-74-8,52866-99-6)

Guidance literature:

o-Toluidin-hydrochlorid, Thionylchlorid, in wsf. Bzl., Erwaermen;

upstream raw materials:

o-toluidine

thionyl chloride

benzene

Downstream raw materials:

3,3'-dimethylazobenzene

1,2-di(p-tolyl)diazene

phenyl-o-tolyl-diazene

2,2'-dimethylazobenzene