Benzene, 1,1'-[oxybis(methylene)]bis[3-nitro-

Base Information

• Chemical Name: Benzene, 1,1'-[oxybis(methylene)]bis[3-nitro-
• CAS No.: 27183-43-3
• Molecular Formula: C14H12N2O5
• Molecular Weight: 288.26
• Mol file: 27183-43-3.mol

Synonyms:Benzene,1,1'-[oxybis(methylene)]bis[3-nitro;1,1'-[oxybis(methylene)]bis[3-nitro-benzene];di(3-nitrobenzyl) ether;Bis-(3-nitro-benzyl)-aether;bis-(3-nitro-benzyl)-ether;Ether,bis(m-nitrobenzyl);Benzene, 1,1‘-[oxybis(methylene)]bis[3-nitro-;

Chemical Property of Benzene, 1,1'-[oxybis(methylene)]bis[3-nitro-

Chemical Property:

• Melting Point: 89.3 °C
• Boiling Point: 457.3±30.0 °C(Predicted)
• PSA: 100.87000
• Density: 1.353±0.06 g/cm3(Predicted)
• LogP: 4.26620

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, 1,1'-[oxybis(methylene)]bis[3-nitro-

There total 6 articles about Benzene, 1,1'-[oxybis(methylene)]bis[3-nitro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

trimethyl(3-nitrobenzyloxy)silane (62673-14-7) → di(3-nitrobenzyl) ether (27183-43-3)

Guidance literature:

With sulfuric acid; silica gel; In hexane; at 20 ℃; for 0.75h;

DOI:10.1055/s-2003-41469

Reference yield: 49.0%

(m-nitrophenyl)diazomethane (19479-81-3) → 3-Nitrobenzyl alcohol (619-25-0) + di(3-nitrobenzyl) ether (27183-43-3) + 1-(fluoromethyl)-3-nitrobenzene (455-94-7)

Guidance literature:

With tetrafluoroboric acid; In dichloromethane; for 0.166667h;

DOI:10.1055/s-1983-30521

Reference yield:

3-nitro-benzaldehyde (99-61-6) → di(3-nitrobenzyl) ether (27183-43-3) + m-nitrobenzyl iodide (3958-56-3)

Guidance literature:

With chloro-trimethyl-silane; 1,1,3,3-Tetramethyldisiloxane; sodium iodide; Yield given. Multistep reaction. Yields of byproduct given; 1.) acetonitrile, room temperature, 10 min, 2.) 30 min, 80 deg C;

DOI:10.1016/S0040-4039(01)80113-1

upstream raw materials:

3-Nitrobenzyl alcohol

hexafluoropropene-diethylamine adduct

(m-nitrophenyl)diazomethane

3-nitro-benzaldehyde

Downstream raw materials:

3-Nitrobenzyl chloride