bis[N-2,6-dimethylphenyl(phenyl)amidato]dibenzyl(tetrahydrofuran)hafnium

Base Information

• Chemical Name: bis[N-2,6-dimethylphenyl(phenyl)amidato]dibenzyl(tetrahydrofuran)hafnium
• CAS No.: 872513-74-1
• Molecular Formula: C₄₈H₅₀HfN₂O₃
• Molecular Weight: 881.427
• Mol file: 872513-74-1.mol

Synonyms:

Chemical Property of bis[N-2,6-dimethylphenyl(phenyl)amidato]dibenzyl(tetrahydrofuran)hafnium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis[N-2,6-dimethylphenyl(phenyl)amidato]dibenzyl(tetrahydrofuran)hafnium

There total 1 articles about bis[N-2,6-dimethylphenyl(phenyl)amidato]dibenzyl(tetrahydrofuran)hafnium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + bis[N-2,6-dimethylphenyl(phenyl)amidato]dibenzylhafnium (872513-77-4) → bis[N-2,6-dimethylphenyl(phenyl)amidato]dibenzyl(tetrahydrofuran)hafnium (872513-74-1)

Guidance literature:

In benzene-d6; under N2; soln. of Hf complex in C6D6 in presnce of THF cooled to <= 0°C; reversible react. on warming; not isolated; detn. by (1)H NMR; Kinetics;

DOI:10.1139/v05-030

Reference yield:

bis[N-2,6-dimethylphenyl(phenyl)amidato]dibenzyl(tetrahydrofuran)hafnium (872513-74-1) + water (7732-18-5) → ([N-2,6-dimethylphenyl(phenyl)amidato]2Hf(μ-O)]4*3(toluene)

Guidance literature:

In water; under N2; slow hydrolysis of Hf complex;

DOI:10.1139/v05-030

Reference yield:

bis[N-2,6-dimethylphenyl(phenyl)amidato]dibenzyl(tetrahydrofuran)hafnium (872513-74-1) + tert-butylisonitrile (119072-55-8,7188-38-7) → [(2,6-dimethylphenylbenzamide(-1H))2Hf(N(t-Bu)CH=CHPh)2] + [(2,6-dimethylphenylbenzamide(-1H))2Hf(η2-(t-Bu)N=CCH2Ph)2] (1239604-82-0)

Guidance literature:

In benzene-d6; (N2); std. Schlenk technique; soln. of isocyanide (2 equiv.) in C6D6 wastransferred to soln. of Hf complex in C6D6 in NMR tube; heated to 80.de gree.C for 24 h; NMR monitoring; not isolated;

DOI:10.1021/om100424j

upstream raw materials:

tetrahydrofuran

bis[N-2,6-dimethylphenyl(phenyl)amidato]dibenzylhafnium

Downstream raw materials:

[(2,6-dimethylphenylbenzamide(-1H))2Hf(η2-(t-Bu)N=CCH2Ph)2]