Carbamic acid, (phenylmethylene)-, methyl ester

Base Information

• Chemical Name: Carbamic acid, (phenylmethylene)-, methyl ester
• CAS No.: 27593-61-9
• Molecular Formula: C9H9NO2
• Molecular Weight: 163.176
• Mol file: 27593-61-9.mol

Synonyms:methyl N-phenylmethylenecarbamate;N-benzylidene methyl carbamate;Carbamic acid,(phenylmethylene)-,methyl ester;benzaldehyde N-carbomethoxy-imine;methyl benzylidenecarbamate;N-methoxycarbonylbenzaldimine;

Chemical Property of Carbamic acid, (phenylmethylene)-, methyl ester

Chemical Property:

• PSA: 38.66000
• LogP: 1.87190

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Carbamic acid, (phenylmethylene)-, methyl ester

There total 8 articles about Carbamic acid, (phenylmethylene)-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

N-benzylidene-1,1,1-trimethylsilanamine (17599-61-0) + methyl chloroformate (79-22-1) → methyl N-phenylmethylenecarbamate (27593-61-9)

Guidance literature:

In chloroform; for 1h; Heating;

DOI:10.1039/c39910000435 DOI:10.1002/chem.19970031019

Reference yield: 70.0%

(E)-N-benzylidene-1,1,1-trimethylsilanamine (120419-97-8) + methyl chloroformate (79-22-1) → benzylidene-carbamic acid methyl ester (27593-61-9)

Guidance literature:

In chloroform; for 3h; Heating;

DOI:10.1039/b102578n

Reference yield:

triphenylphosphine (603-35-0) + N-tert-butyloxycarbonyl-3-(4-cyanophenyl)oxaziridine (150884-56-3,158807-35-3) → methyl N-phenylmethylenecarbamate (27593-61-9) + triphenyl(t-butoxycarbonylimino)phosphorane (68014-21-1) + 4-cyanobenzaldehyde (105-07-7) + Triphenylphosphine oxide (791-28-6)

Guidance literature:

In chloroform-d1; at 19 ℃; Product distribution; other solvents, temperature;

DOI:10.1002/chem.19970031019

upstream raw materials:

methyl N-(1-ethoxy-1-phenylmethyl)carbamate

N-benzylidene-1,1,1-trimethylsilanamine

methyl chloroformate

N-methoxycarbonyl-3-phenyloxaziridine

Downstream raw materials:

(1α,3β,4α)-1,5,6-Tri-tert-butyl-3-phenyl-2-azabicyclo<2.2.0>hex-5-en-2,4-dicarbonsaeure-2-methylester-4-tert-butylester

1,2,6-Tri-tert-butyl-4-phenyl-3-azatricyclo<3.1.0.0^2,6>hexan-3,5-dicarbonsaeure-3-methylester-5-tert-butylester

3-Methoxycarbonylamino-2-methyl-3-phenyl-dithiopropionic acid methyl ester

N-methoxycarbonyl benzamide