1,5-Diiodonaphthalene

Base Information

• Chemical Name: 1,5-Diiodonaphthalene
• CAS No.: 27715-44-2
• Molecular Formula: C10H6I2
• Molecular Weight: 379.96400
• Hs Code.: 2903999090
• DSSTox Substance ID: DTXSID60396638
• Nikkaji Number: J402.540G
• Wikidata: Q82197449
• Mol file: 27715-44-2.mol

Synonyms:1,5-diiodonaphthalene;27715-44-2;C10H6I2;Naphthalene, 1,5-diiodo-;SCHEMBL1269977;DTXSID60396638;KFRJPQOLRHRVIS-UHFFFAOYSA-N;MFCD00667760;AKOS015998874;AS-18259;Y1S00020;CS-0170442;FT-0688717;C90444

Chemical Property of 1,5-Diiodonaphthalene

Chemical Property:

• Melting Point: 147 °C
• Boiling Point: 384.2±15.0 °C(Predicted)
• PSA: 0.00000
• Density: 2.265±0.06 g/cm3(Predicted)
• LogP: 4.04900
• Storage Temp.: 2-8°C
• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 379.85590
• Heavy Atom Count: 12
• Complexity: 140

Purity/Quality:

99%, ^*data from raw suppliers

1,5-Diiodonaphthalene 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C=CC=C2I)C(=C1)I

Technology Process of 1,5-Diiodonaphthalene

There total 6 articles about 1,5-Diiodonaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

1,5-naphthalenediamine (2243-62-1) → 1,5-diiodonaphthalene (27715-44-2)

Guidance literature:

With urea; potassium iodide; sodium nitrite; In sulfuric acid; water; acetic acid; at 0 ℃;

DOI:10.1021/jo0203589

Reference yield: 75.0%

1,5-dibromonaphthalene (7351-74-8) → 1,5-diiodonaphthalene (27715-44-2)

Guidance literature:

With copper(l) iodide; potassium iodide; In N,N,N,N,N,N-hexamethylphosphoric triamide; at 150 - 160 ℃; for 6h;

DOI:10.1055/s-1986-31491

Reference yield: 70.0%

naphthalene-1,5-disulphonyl chloride (1928-01-4) → 1,5-diiodonaphthalene (27715-44-2)

Guidance literature:

With bis(benzonitrile)palladium(II) dichloride; Ti(Oi-Pr); lithium chloride; zinc(II) iodide; In 1,2-dimethoxyethane; at 162 ℃;

DOI:10.1246/bcsj.66.2121

upstream raw materials:

1,5-naphthalenediamine

1,5-dibromonaphthalene

naphthalene-1,5-disulphonyl chloride

1,5-dinitronaphthalene

Downstream raw materials:

1,5-bis[(3,5-bis-trimethylsilylethynylphenyl)ethynyl]naphthalene

1,5-bis-[4-(3,5-bis-trimethylsilanylethynyl-phenylethynyl)-phenylethynyl]-naphthalene

1,5-bis(phenylethynyl)naphthalene

1,5-bis((diphenylphosphino)ethynyl)naphthalene