chloro(triphenylphosphine)bis[2-(m-tolylazo)pyridine]ruthenium(II)perchlorate hydrate

Base Information

• Chemical Name: chloro(triphenylphosphine)bis[2-(m-tolylazo)pyridine]ruthenium(II)perchlorate hydrate
• CAS No.: 81554-93-0
• Molecular Formula: C₄₂H₃₇ClN₆PRu*ClO₄*H₂O
• Molecular Weight: 910.759
• Mol file: 81554-93-0.mol

Synonyms:

Chemical Property of chloro(triphenylphosphine)bis[2-(m-tolylazo)pyridine]ruthenium(II)perchlorate hydrate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of chloro(triphenylphosphine)bis[2-(m-tolylazo)pyridine]ruthenium(II)perchlorate hydrate

There total 1 articles about chloro(triphenylphosphine)bis[2-(m-tolylazo)pyridine]ruthenium(II)perchlorate hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

trans-trans-di(Cl)bis(2-(m-tolylazo)pyridine)ruthenium(II) (105881-11-6,648928-36-3,77321-09-6,81600-80-8,84049-23-0) + sodium perchlorate → chloro(triphenylphosphine)bis[2-(m-tolylazo)pyridine]ruthenium(II)perchlorate hydrate (81554-93-0)

Guidance literature:

With triphenylphosphine; In methanol; water; PPh3 was added to a suspn. of complex in 1:1 methanol-water mixture, refluxed for 4 h, poured a filtered soln. into aq. NaClO4 and kept in the refrigerator for 2-3 h; filtration, washing a ppt. with water and diethyl ether, drying over P4O10 in vac., column chromy. (silica gel, benzene-acetonitrile, 9:1, then3:2); elem. anal.;

DOI:10.1021/ic00137a040

upstream raw materials:

trans-trans-di(Cl)bis(2-(m-tolylazo)pyridine)ruthenium(II)