1-(2,2-Difluoroethenyl)-4-methylbenzene

Base Information

Chemical Name:1-(2,2-Difluoroethenyl)-4-methylbenzene
CAS No.:28321-07-5
Molecular Formula:C9H8F2
Molecular Weight:154.159
Hs Code.:
DSSTox Substance ID:DTXSID80423697
Nikkaji Number:J914.800K
Mol file:28321-07-5.mol

Synonyms:1-(2,2-Difluoroethenyl)-4-methylbenzene;28321-07-5;SCHEMBL17877589;DTXSID80423697;HPGPTXFIZSTWBT-UHFFFAOYSA-N;beta,beta-Difluoro-4-methylstyrene

Suppliers and Price of 1-(2,2-Difluoroethenyl)-4-methylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 1-(2,2-Difluoroethenyl)-4-methylbenzene

Chemical Property:

XLogP3:3.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:154.05940658
Heavy Atom Count:11
Complexity:140

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)C=C(F)F

Technology Process of 1-(2,2-Difluoroethenyl)-4-methylbenzene

There total 17 articles about 1-(2,2-Difluoroethenyl)-4-methylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1241999-21-2
2,2-difluorovinyl mesylate

: 5720-05-8
4-methylphenylboronic acid

: 28321-07-5
1-(2,2-difluorovinyl)-4-methylbenzene

Guidance literature:: With sodium tetrachloropalladate(II); cataCXium F sulf; potassium carbonate; In water; at 100 ℃; for 16h; Inert atmosphere;
DOI:10.1039/b924772f

Reference yield: 80.0%

: 624-31-7
4-tolyl iodide

: 101032-99-9
2,2-difluorovinylzinc chloride

: 28321-07-5
1-(2,2-difluorovinyl)-4-methylbenzene

Guidance literature:: With sulfuric acid; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; for 2h; Ambient temperature;
DOI:10.1016/0022-328X(87)80001-3

Reference yield: 70.0%

: 104-87-0
4-methyl-benzaldehyde

: 58310-28-4
(Difluoromethyl)triphenylphosphonium bromide

: 28321-07-5
1-(2,2-difluorovinyl)-4-methylbenzene

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In N,N-dimethyl-formamide; at 50 ℃; for 4h; Inert atmosphere;
DOI:10.1016/j.jfluchem.2014.04.011