alpha-(2-Naphthyl)styrene

Base Information

• Chemical Name: alpha-(2-Naphthyl)styrene
• CAS No.: 28358-66-9
• Molecular Formula: C18H14
• Molecular Weight: 230.309
• DSSTox Substance ID: DTXSID501306107
• Nikkaji Number: J603.405E
• Mol file: 28358-66-9.mol

Synonyms:2-(1-phenylethenyl)naphthalene;alpha-(2-Naphthyl)styrene;2-(1-phenylethenyl) naphthalene;TVGRJLSFATZNPC-UHFFFAOYSA-N;1-(2-naphthyl)-1-phenylethylene;DTXSID501306107;28358-66-9

Chemical Property of alpha-(2-Naphthyl)styrene

Chemical Property:

• XLogP3: 6.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 230.109550447
• Heavy Atom Count: 18
• Complexity: 284

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=C(C1=CC=CC=C1)C2=CC3=CC=CC=C3C=C2

Technology Process of alpha-(2-Naphthyl)styrene

There total 34 articles about alpha-(2-Naphthyl)styrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

bicyclo[2.2.1]hepta-2,5-diene (121-46-0) + 1-Iodo-2-(3-phenyl-buta-1,2-dienyl)-benzene (180138-12-9) → 1-(2-naphthyl)styrene (28358-66-9)

Guidance literature:

With tetraethylammonium chloride; potassium carbonate; triphenylphosphine; palladium diacetate; In acetonitrile; for 20h; Heating;

DOI:10.1016/0040-4039(96)00809-X

Reference yield: 92.0%

1-(naphthalen-2-yl)vinyl diphenyl phosphate + phenylboronic acid (98-80-6) → 1-(2-naphthyl)styrene (28358-66-9)

Guidance literature:

With potassium phosphate; tricyclohexylphosphine tetrafluoroborate; bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; In tetrahydrofuran; at 65 ℃; for 16h;

DOI:10.1039/b609064h

Reference yield: 91.0%

triphenylboroxine (3262-89-3) + methyl 2-naphthyl ketone (93-08-3) → 1-(2-naphthyl)styrene (28358-66-9)

Guidance literature:

With tetrakis(triphenylphosphine)nickel⁽⁰⁾; water; 1,2-bis-(dicyclohexylphosphino)ethane; In diethylene glycol dimethyl ether; at 110 ℃; for 24h; Glovebox; Schlenk technique; Inert atmosphere;

DOI:10.1021/jacs.7b02742

upstream raw materials:

methyl 2-naphthyl ketone

2-naphthyl triflate

1-methyldifluorosilylstyrene

naphthalene

Downstream raw materials:

7-Phenyldibenzophenanthrene-9,14-dione

5-(2-Naphthyl)benzanthracene-7,12-dione

1-(2-naphthyl)-1-phenyl ethane

1-(2-naphthyl)-1-phenyl-2,2-dibromocyclopropane