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SULFUR CHLORIDE PENTAFLUORIDE

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Name

SULFUR CHLORIDE PENTAFLUORIDE

EINECS N/A
CAS No. 13780-57-9 Density N/A
PSA 25.30000 LogP 3.43870
Solubility N/A Melting Point -64°C
Formula ClF5 S Boiling Point -21°C
Molecular Weight 162.511 Flash Point N/A
Transport Information N/A Appearance N/A
Safety Poison by inhalation. An irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Cl, F, and SOx. See also FLUORIDES. Risk Codes 23-34
Molecular Structure Molecular Structure of 13780-57-9 (SULPHUR CHLOROPENTAFLUORIDE) Hazard Symbols
Synonyms

Sulfurchloride fluoride (SClF5) (6CI,7CI); Chloropentafluorosulfur;Monochloropentafluorosulfur; Pentafluorosulfur chloride; Sulfur chloridepentafluoride; Sulfur monochloride pentafluoride; Sulfur pentafluoride chloride

Article Data 12

SULFUR CHLORIDE PENTAFLUORIDE Synthetic route

13997-90-5

chlorine fluorosulfate

7783-60-0

sulfur tetrafluoride

A

13780-57-9

pentafluorosulfanyl chloride

B

88548-61-2

trifluorosulfonium fluorosulfate

Conditions
ConditionsYield
In neat (no solvent) ClOSO2F trasferred under vac. to FEP reactor fitted with stainless-steel valve and held at -196°C, SF4 condensed, reactor placed in bath at -90°C and allowed to warm to -40°C for 4 h; reactor cooled to -70°C, volatile materials(SF5Cl) removed, reactor warmed to -40°C and then - to 23°C and held under dynamic vac. for 10 min;A 77%
B 38%

potassium fluoride

87-90-1

trichloroisocyanuric acid

A

640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

B

13780-57-9

pentafluorosulfanyl chloride

C

7783-42-8

thionyl fluoride

Conditions
ConditionsYield
In acetonitrile at 20℃; Inert atmosphere; Darkness; Sealed tube;A n/a
B 47%
C n/a
7790-91-2

chlorine trifluoride

7783-60-0

sulfur tetrafluoride

13780-57-9

pentafluorosulfanyl chloride

Conditions
ConditionsYield
In neat (no solvent) between 100 - 350°C under exclusion of water at 3 atm;;
In neat (no solvent) between 100 - 350°C under exclusion of water at 3 atm;;
7783-60-0

sulfur tetrafluoride

7790-89-8

chlorine monofluoride

13780-57-9

pentafluorosulfanyl chloride

Conditions
ConditionsYield
In neat (no solvent) at 100 - 300°C and 3 atm;;
In gaseous matrix Kinetics; Irradiation (UV/VIS); photochemical reaction (Ar laser, mean power 10 mW, 450-500 nm, 100 Torr xenon as buffer gas); not isolated; IR monitoring;
In neat (no solvent) at 100 - 300°C and 3 atm;;
5714-22-7

disulfur decafluoride

13780-57-9

pentafluorosulfanyl chloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) passing Cl2 and S2F10 through tube at 350°C;;
With chlorine In neat (no solvent) passing Cl2 and S2F10 through tube under reduced pressure;;>99
10025-67-9

disulfur dichloride

22650-46-0

F5SNCl2

A

13780-57-9

pentafluorosulfanyl chloride

B

25502-15-2

SF5N=SCl2

Conditions
ConditionsYield
In further solvent(s) Cl2S2 is placed in a FEP-trap (dry-box), evacuated and cooled to -196°C, CFCl3 is condensed into trap, mixt. is warmed to room temp., into this mixt. Fe5SNCl2 is condensed (liquid N2), cooling to -100°C, mixt. is allowed to warm; mixt. is stirred under warming to -20°C for several hours, sepn.by fractional condensation in oil vac. in cold traps at -45, -50, -196°C, react. is followed by Raman-spectroscopy;
60563-08-8

dichlorodithionitronium hexafluoroarsenate

7790-89-8

chlorine monofluoride

A

13780-57-9

pentafluorosulfanyl chloride

B

30313-36-1

{SF3}(1+)*{AsF6}(1-)=SF3AsF6

C

difluoro-dithionitronium hexafluoroarsenate(V)

D

7783-60-0

sulfur tetrafluoride

E

7783-42-8

thionyl fluoride

Conditions
ConditionsYield
With fluorosulfonylchloride In not given SO2ClF and ClF were condensed onto (SCl)2NAsF6, mixt. was warmed to room temp. with srirring, 5 h; volatiles were removed, products were not isolated; products were analized by IR;A n/a
B n/a
C 0%
D n/a
E <1

potassium fluoride

87-90-1

trichloroisocyanuric acid

7704-34-9

sulfur

13780-57-9

pentafluorosulfanyl chloride

Conditions
ConditionsYield
With trifluoroacetic acid In acetonitrile at 20℃; for 14h; Inert atmosphere;
13780-57-9

pentafluorosulfanyl chloride

22650-46-0

F5SNCl2

100312-09-2

tris(pentafluorosulfanyl)amine

Conditions
ConditionsYield
In water at 20℃; under 1.50015 Torr; for 3.5h; UV-irradiation;94%
13780-57-9

pentafluorosulfanyl chloride

22675-70-3

pentafuorosulfanyl hypochlorite

42310-84-9

bis(pentafluorosulfur)oxide

Conditions
ConditionsYield
byproducts: SO2F2, SOF4, SF6; Irradiation (UV/VIS); irradn. for 4 h at 22°C; collection in a -196°C trap (dynamic vacuum); fractional condensation; SF5OSF5 and SF5O2SF5 in -111°C trap; mixt. heated in copper reactor at 237°C for 2.5 h;; fractional condensation yielded SF5OSF5 in a -118°C trap; further compounds (from decompn. of SF5O2SF5) in -196°C trap;;72%

SULFUR CHLORIDE PENTAFLUORIDE Chemical Properties

Product Name: Sulphur chloropentafluoride
Synonyms:Chloropentafluorosulfur ; Monochloropentafluorosulfur ; Pentafluorosulfurchloride ; SClF5 ; SF5Cl ; Silfur chloropentafluoride ; Sulfur chloride fluoride ; Sulfur chloride fluoride (SClF5).
CAS: 13780-57-9
Molecular Formula of Sulphur chloropentafluoride (13780-57-9) : ClF5S
Molecular Weight of Sulphur chloropentafluoride (13780-57-9) : 162.51
Molecular Struture of Sulphur chloropentafluoride (13780-57-9) :
EINECS: 237-431-0
Product Categories:
Mol File: 13780-57-9.mol
Melting point: -64°C
Boiling point: -21°C

SULFUR CHLORIDE PENTAFLUORIDE Toxicity Data With Reference

1.    

ihl-rat LCLo:100 ppm/1H

    BJIMAG    British Journal of Industrial Medicine. 27 (1970),1.

SULFUR CHLORIDE PENTAFLUORIDE Safety Profile

Hazard Codes  T
Risk Statements  23-34
23:  Toxic by inhalation 
34:   Sulphur chloropentafluoride (13780-57-9) causes burns 
Safety Statements  26-36/37/39-45
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection  
RIDADR  3308
Hazard Note  Toxic

SULFUR CHLORIDE PENTAFLUORIDE Standards and Recommendations

OSHA PEL: TWA 2.5 mg(F)/m3
ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: (Inorganic Fluorides) TWA 2.5 mg(F)/m3

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