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Sulfur fluoride oxide(SF4O), (SP-5-21)-

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Name

Sulfur fluoride oxide(SF4O), (SP-5-21)-

EINECS N/A
CAS No. 13709-54-1 Density g/cm3
PSA 36.28000 LogP 2.21020
Solubility N/A Melting Point N/A
Formula F4O S Boiling Point °Cat760mmHg
Molecular Weight 124.059 Flash Point °C
Transport Information N/A Appearance N/A
Safety
Risk Statements 26-34
Safety Statements 26-36/37/39-45
RIDADR 3308
Risk Codes 26-34
Molecular Structure Molecular Structure of 13709-54-1 (SULFURYL OXYTETRAFLUORIDE) Hazard Symbols N/A
Synonyms

Sulfurfluoride oxide (SOF4) (7CI,8CI); Sulfur oxyfluoride (SOF4) (6CI); Sulfurfluoride oxide (SF4O); Sulfur oxytetrafluoride (SOF4); Sulfur tetrafluoridemonoxide; Sulfur tetrafluoride oxide; Thionyl tetrafluoride

Article Data 31

Sulfur fluoride oxide(SF4O), (SP-5-21)- Synthetic route

7782-41-4

fluorine

7783-42-8

thionyl fluoride

A

15179-32-5

pentafluorosulfur hypofluorite

13709-54-1

thionyl tetrafluoride

Conditions
ConditionsYield
In neat (no solvent) Electrochem. Process; silent discharge;;
In neat (no solvent) Electrochem. Process; silent discharge;;
7782-41-4

fluorine

7783-42-8

thionyl fluoride

A

640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

13709-54-1

thionyl tetrafluoride

C

7783-61-1

silicon tetrafluoride

D

2551-62-4

sulphur hexafluoride

Conditions
ConditionsYield
With SiO2 In neat (no solvent, gas phase) introduction of F2 stream into liquid SOF2 (-50°C); mixture (F2/SOF2) escapes into quartz tube (containing heated Pt net/150°C); pale red flame observed; abs. exclusion of air;; condensed (liquid air cooling); removal of F2 (water jet pump/-190°C); fractionated (quartz column);;
7782-41-4

fluorine

7783-42-8

thionyl fluoride

A

640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

13709-54-1

thionyl tetrafluoride

C

2551-62-4

sulphur hexafluoride

Conditions
ConditionsYield
In neat (no solvent) mixture with fair excess of F2 in warmed quartz tube; slowly at common temps.;;
7782-41-4

fluorine

7783-42-8

thionyl fluoride

13709-54-1

thionyl tetrafluoride

Conditions
ConditionsYield
In neat (no solvent) common temps., glass vessel;;
In neat (no solvent) common temps., glass vessel;;

silver(II) fluoride

7782-41-4

fluorine

7783-42-8

thionyl fluoride

A

15179-32-5

pentafluorosulfur hypofluorite

13709-54-1

thionyl tetrafluoride

Conditions
ConditionsYield
In neat (no solvent) passing N2/SOF2/F2 over AgF2 at 200°C;;
In neat (no solvent) passing N2/SOF2/F2 over AgF2 at 200°C;;
17023-34-6

F5OS(1-)

7783-61-1

silicon tetrafluoride

13709-54-1

thionyl tetrafluoride

B

F5Si(1-)

Conditions
ConditionsYield
In gas Kinetics; reaction studied over the range 299-387 K;
508233-73-6

pentafluoronitrosulfane

A

5714-22-7

disulfur decafluoride

13709-54-1

thionyl tetrafluoride

C

10102-44-0

Nitrogen dioxide

Conditions
ConditionsYield
In neat (no solvent, gas phase) Kinetics; byproducts: FNO; decompn. at room temp.; not isolated;
15607-89-3

pentafluorosulfanyl bromide

10102-44-0

Nitrogen dioxide

A

5714-22-7

disulfur decafluoride

B

508233-73-6

pentafluoronitrosulfane

13709-54-1

thionyl tetrafluoride

D

7783-60-0

sulfur tetrafluoride

E

2551-62-4

sulphur hexafluoride

Conditions
ConditionsYield
In neat (no solvent) byproducts: Br2, FNO; Irradiation (UV/VIS); irradiated for 12 h with λmax = 420 nm; condensed into a cylinder held at -196°C, vac. transferred into another cylinder, condensed several times (trap-to-trap); obtained with apurity of ca 98%;
22675-70-3

pentafuorosulfanyl hypochlorite

2696-92-6

nitrosylchloride

13709-54-1

thionyl tetrafluoride

B

SF5ONO

Conditions
ConditionsYield
In not given byproducts: Cl2, FNO;A n/a
B 0%
13709-54-1

thionyl tetrafluoride

42005-82-3

N-Trimethylsilylaminotellurpentafluorid

A

42005-83-4

pentafluorotelluroamine

B

420-56-4

trimethylsilyl fluoride

C

86024-53-5

OSF2NTeF5

Conditions
ConditionsYield
In neat (no solvent) (CH3)3SiNHTeF5 filled into autoclave prior to addn. at -196°C SOF4 and mixt. slowly warmed to 65°C and stirred for 40 h; volatile materials pumped into -196°C cooled trap, vac. distillation through -25, -78 (O=SF2=NTeF5) and -196°C ((CH3)3SiF and SOF4) trap; elem. anal.;A n/a
B n/a
C 83%
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