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Cas Database |
| Name |
Tri(2-furyl)phosphine |
EINECS | 628-036-8 |
| CAS No. | 5518-52-5 | Density | N/A |
| PSA | 53.01000 | LogP | 2.22380 |
| Solubility | N/A | Melting Point |
59-64 °C(lit.) |
| Formula | C12H9O3P | Boiling Point | 286.4 °C at 760 mmHg |
| Molecular Weight | 232.175 | Flash Point | 127 °C |
| Transport Information | N/A | Appearance | white to light yellow crystal powder |
| Safety | 26-24/25 | Risk Codes | 36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
Phosphine,tri-2-furyl- (7CI,8CI);Tri-2-furanylphosphine;Tri-2-furylphosphine;Tris(2-furanyl)phosphine;Tris(2-furyl)phosphine;Tris(o-furyl)phosphine;Tri(2-furyl)phosphine; |
Article Data | 12 |
Tri(2-furyl)phosphine Chemical Properties
Systematic Name: Trifuran-2-ylphosphane
SMILES: o1cccc1P(c2occc2)c3occc3
InChI: InChI=1/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H
InChIKey: DLQYXUGCCKQSRJ-UHFFFAOYAK
Empirical Formula: C12H9O3P
Molecular Weight: 232.1718
color: faintly brown
Melting Point: 59-64 °C(lit.)
Flash Point: 127 °C
Enthalpy of Vaporization: 50.44 kJ/mol
Boiling Point: 286.4 °C at 760 mmHg
Vapour Pressure: 0.00456 mmHg at 25 °C
Product Categories of Phosphine,tri-2-furanyl- (CAS NO.5518-52-5): Ligand; Phosphine Ligands; Synthetic Organic Chemistry; Catalysis and Inorganic Chemistry; Phosphine Ligands; Phosphorus Compounds
Tri(2-furyl)phosphine Uses
A phopshine ligand used in transition-metal mediated organic synthesis, in particular in wittig reactions to improved (Z) selectivity.
Tri(2-furyl)phosphine Safety Profile
Hazard Codes: 
Xi
Risk Statements: 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements of Phosphine,tri-2-furanyl- (CAS NO.5518-52-5): 26-24/25
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24/25:Avoid contact with skin and eyes.
WGK Germany: 3
Tri(2-furyl)phosphine Specification
Phosphine,tri-2-furanyl- (CAS NO.5518-52-5), its Synonyms are Tri(2-furyl)phosphine ; Tri-(2-furyl)phosphine ; Tris(2-furyl)phosphine ; Tri-2-furylphosphine ; Tris-furan-2-yl-phosphine . It is white to light yellow crystal powder.
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