Hot Products

Basic Information

Post buying leads

Suppliers

Cas Database

Name	Tri-n-hexylaluminium	EINECS	214-241-6
CAS No.	1116-73-0	Density	g/cm³
PSA	0.00000	LogP	7.60290
Solubility	N/A	Melting Point	-87oC
Formula	C18H39 Al	Boiling Point	68.5 °C at 760 mmHg
Molecular Weight	282.489	Flash Point	°C
Transport Information	N/A	Appearance	clear colorless solution
Safety	6A-61-45-43B-36/37/39-24/25-16	Risk Codes	67-65-62-51/53-48/20-34-14/15-11
Molecular Structure		Hazard Symbols	NCF
Synonyms	Tri-n-hexylaluminum;Tri-n-hexylaluminum (Al(C6H13)3); Trihexylalane; Trihexylaluminum	Article Data	13

Tri-n-hexylaluminium Synthetic route

: 16853-85-3
lithium aluminium tetrahydride

: 592-41-6
1-hexene

: 2674-15-9
di(n-hexyl)aluminum chloride

: 1116-73-0
trihexylaluminium

Conditions

Conditions	Yield
In n-heptane byproducts: LiCl; LiAlH4 loaded in a vertical-type ball mill under Ar or N2; heptane added; mixt. agitated for 15 min at 70°C; mixt. of (C6H13)2AlCl with hex-1-ene (LiAlH4:(C6H13)2AlCl:hex-1-ene=1.1:1.0:4.5) added; mixt. agitated for 1.5 h at 90°C; cooled; filtered under Ar; solvent and olefin removed (vac., 10 Torr) at60-70°C; elem. anal.;	95%

: aluminium hydride

: 592-41-6
1-hexene

: 1116-73-0
trihexylaluminium

Conditions

Conditions	Yield
With triisobutylaluminum In hexane (N2); heating (autoclave, 140°C, 1 h, 120°C, 8 h); distn.; elem. anal.;	89.1%
With NaAlEt4 In toluene under N2 or Ar; mixt. of AlH3, NaAlEt4, olefin (3.8 equiv.) and toluene heated at reflux; after 20 min temp. raised from 80 to 100°C and gradually decreased to 70-80°C; 2 h; cooled; filtered; ppt. washed with hexane; solvent and excess olefin removed in vac. at 60-80°C (7 Torr); elem. anal.;

: 592-47-2
3-hexene

: 102-67-0
tri-n-propylaluminum

: 1116-73-0
trihexylaluminium

Conditions

Conditions	Yield
Stage #1: 3-hexene; tri-n-propylaluminum at 70℃; under 760.051 Torr; Heating / reflux; Stage #2: cobalt(III) acetylacetonate In toluene for 2h; Stage #3: With hydrogenchloride	6.1%

: 592-41-6
1-hexene

: 1116-73-0
trihexylaluminium

Conditions

Conditions	Yield
With aluminium hydride
With lithium aluminium tetrahydride

: 1116-73-0
trihexylaluminium

: 75-36-5
acetyl chloride

: 111-13-7
hexyl-methyl-ketone

Conditions

Conditions	Yield
With aluminium trichloride In dichloromethane for 1h; Product distribution; Ambient temperature; other reaction time; other reagent: ZnCl2; other molecular proportion.;	90%
With aluminium trichloride In dichloromethane for 1h; Ambient temperature;	90%

: 1185-96-2
3-acetoxy-3-ethylbutyne

: 1116-73-0
trihexylaluminium

A: 3-methyl-3,4-undecadiene

B (n-C6H13)2AlOAc: (n-C6H13)2AlOAc

Conditions

Conditions	Yield
With iron(III) chloride In various solvent(s) at 40℃; for 15h;	A 86% B n/a

: 1116-73-0
trihexylaluminium

: 98-88-4
benzoyl chloride

: 1671-75-6
Heptanophenone

Conditions

Conditions	Yield
With aluminium trichloride In dichloromethane for 1h; Product distribution; Ambient temperature; other molecular proportion.;	84%
With aluminium trichloride In dichloromethane for 1h; Ambient temperature;	84%

: 216586-53-7
(1R,2R)-trans-N-phthaloyl-1,2-diaminocyclohexane

: 1116-73-0
trihexylaluminium

: C34H46N2O4

Conditions

Conditions	Yield
In toluene at -5 - 50℃; for 7h; Inert atmosphere;	81.8%
In toluene at -5 - 50℃; for 7h; Inert atmosphere;	81.8%

: 16212-05-8
(allylsulfonyl)benzene

: 1116-73-0
trihexylaluminium

: 124-11-8
non-1-ene

Conditions

Conditions	Yield
With dilithium tetrachlorocuprate; triphenylphosphine In octane at 50℃; for 5h;	78%

: 592-41-6
1-hexene

: 1116-73-0
trihexylaluminium

: 123-72-8
butyraldehyde

: 6-butyl-7-methylundecan-4-ol

Conditions

Conditions	Yield
Stage #1: 1-hexene; trihexylaluminium With zirconocene dichloride In hexane at 0 - 20℃; Stage #2: butyraldehyde With copper(l) chloride In hexane at -15 - 20℃;	78%

Tri-n-hexylaluminium Chemical Properties

Molecular structure of Tri-n-hexylaluminium (CAS NO.1116-73-0) is:

Product Name: Tri-n-hexylaluminium
CAS Registry Number: 1116-73-0
IUPAC Name: Trihexylalumane
Molecular Weight: 282.483798 [g/mol]
Molecular Formula: C₁₈H₃₉Al
H-Bond Donor: 0
H-Bond Acceptor: 0
EINECS: 214-241-6
Density: 0.686 g/cm³
Storage temp.: Flammables + water-Freezer (-20 °C)e area
Product Categories: Organometallics
Canonical SMILES: CCCCCC[Al](CCCCCC)CCCCCC
InChI: InChI=1S/3C6H13.Al/c3*1-3-5-6-4-2;/h3*1,3-6H2,2H3;
InChIKey: ORYGRKHDLWYTKX-UHFFFAOYSA-N

Tri-n-hexylaluminium Safety Profile

Safty information about Tri-n-hexylaluminium (CAS NO.1116-73-0) is:
Hazard Codes: Dangerous N; Corrosive C; Flammable F
Risk Statements: 67-65-62-51/53-48/20-34-14/15-11
R67:Vapours may cause drowsiness and dizziness.
R65:Harmful: may cause lung damage if swallowed.
R62:Risk of impaired fertility.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R48/20:Danger of serious damage to health by prolonged exposure and harmful by inhalation.
R34:Causes burns.
R14/15 :Reacts violently with water and contact with water liberates extremely flammable gases.
R11:Highly flammable.
Safety Statements: 6A-61-45-43B-36/37/39-24/25-16
S6:Keep under ... (there follows the name of an inert gas).
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S24/25:Avoid contact with skin and eyes.
S16:Keep away from sources of ignition.
RIDADR: 3051
HazardClass: 4.2
PackingGroup: I

Tri-n-hexylaluminium Specification

Tri-n-hexylaluminium , its cas register number is 1116-73-0. It also can be called Trihexylalane ; Aluminum, trihexyl- ; Trihexylaluminium .It is a clear colorless solution.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 1116-73-0