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Cas Database |
| Name |
Triethyl methanetricarboxylate |
EINECS | 228-477-2 |
| CAS No. | 6279-86-3 | Density | 1.136 g/cm3 |
| PSA | 78.90000 | LogP | 0.29190 |
| Solubility | immiscible with water | Melting Point |
25-26 °C(lit.) |
| Formula | C10H16O6 | Boiling Point | 281.3 °C at 760 mmHg |
| Molecular Weight | 232.233 | Flash Point | 118.3 °C |
| Transport Information | N/A | Appearance | clear colorless to yellow liquid after melting |
| Safety | 23-24/25 | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Methanetricarboxylicacid, triethyl ester (7CI,8CI,9CI);Diethyl (carboethoxy)malonate;Diethyl(ethoxycarbonyl)malonate;Diethyl 2-ethoxycarbonylmalonate;NSC 11006;Tri(ethoxycarbonyl)methane;Tricarboethoxymethane;Tris(ethoxycarbonyl)methane; |
Article Data | 23 |
Triethyl methanetricarboxylate Synthetic route
- 930297-54-4
2-(indoline-1-carbonyl)-3-(indolin-1-yl)-3-oxopropionic acid
A
- 649765-74-2
methanetri-N-(indolin-1-yl)carboxamide
B
- 6279-86-3
methanetricarboxylic acid triethyl ester
| Conditions | Yield |
|---|---|
| at 220℃; | A 85% B n/a |
- 16515-85-8
triethyl pent-4-ene-1,2,2-tricarboxylate
- 6279-86-3
methanetricarboxylic acid triethyl ester
| Conditions | Yield |
|---|---|
| With titanium(IV) isopropylate; isopropylmagnesium chloride In diethyl ether at -50 - -40℃; for 1h; deallylation; | 83% |
- 541-41-3
chloroformic acid ethyl ester
- 105-53-3
diethyl malonate
- 6279-86-3
methanetricarboxylic acid triethyl ester
| Conditions | Yield |
|---|---|
| With magnesium oxide In toluene at 80 - 83℃; for 7h; further reag.: Mg(OH)2, K2CO3, Et3N, pyridine,; add of Bu4NCl,MgCl2; var solv. temp. and time; | 71% |
| Stage #1: diethyl malonate With magnesium ethylate In ethanol at 80℃; for 2h; Stage #2: chloroformic acid ethyl ester In tetrahydrofuran; tetrachloromethane; ethanol for 1h; Heating; | 71% |
| With magnesium oxide In toluene at 80℃; for 7h; Temperature; | 65% |
- 543-27-1
isobutyl chloroformate
A
- 6279-86-3
methanetricarboxylic acid triethyl ester
B
- 125563-02-2
diethyl isobutyl methanetricarboxylate
C
- 125563-03-3
ethyl-diisobutyl methanetricarboxylate
| Conditions | Yield |
|---|---|
| With magnesium oxide In toluene at 80 - 83℃; for 7h; | A 1.5% B 69% C 2.7% |
A
- 6279-86-3
methanetricarboxylic acid triethyl ester
B
- 211992-53-9
diethyl [2-(ethoxycarbonyl)-3-phenyl-2-(E)-propenyl]malonate
| Conditions | Yield |
|---|---|
| With titanium(IV) isopropylate; isopropylmagnesium chloride In diethyl ether at -50 - -40℃; for 1h; Rearrangement; depropargylation; | A 19% B 57% |
- 72091-41-9
(Oxomethylen)malonsaeure-diethylester
- 64-17-5
ethanol
- 6279-86-3
methanetricarboxylic acid triethyl ester
- 72091-41-9
(Oxomethylen)malonsaeure-diethylester
- 6279-86-3
methanetricarboxylic acid triethyl ester
| Conditions | Yield |
|---|---|
| at 180℃; | |
| at 180℃; | |
| With ethanol |
- 854747-47-0
bromo-methanetricarboxylic acid triethyl ester
- 996-82-7
sodium diethylmalonate
A
- 6279-86-3
methanetricarboxylic acid triethyl ester
B
- 632-56-4
tetraethyl ethane-1,1,2,2-tetracarboxylate
- 39000-70-9
methanetetracarboxylic acid tetraethyl ester
- 6279-86-3
methanetricarboxylic acid triethyl ester
| Conditions | Yield |
|---|---|
| With alkali |
- 996-82-7, 34727-00-9, 73177-21-6
sodium diethylmalonate
- 541-41-3
chloroformic acid ethyl ester
- 6279-86-3
methanetricarboxylic acid triethyl ester
| Conditions | Yield |
|---|---|
| With benzene |
Triethyl methanetricarboxylate Chemical Properties
Molecular Structure of Methanetricarboxylicacid, 1,1,1-triethyl ester (CAS NO.6279-86-3):
.png)
Molecular Formula: C10H16O6
Molecular Weight: 232.2304
IUPAC Name: Triethyl methanetricarboxylate
Synonyms of Methanetricarboxylicacid, 1,1,1-triethyl ester (CAS NO.6279-86-3): AI3-18421 ; EINECS 228-477-2 ; Methanetricarboxylic acid, triethyl ester ; Triethyl methanetricarboxylate
CAS NO: 6279-86-3
Classification Code: C10 to C11 ; Carbonyl Compounds ; Esters
Melting point: 25-26 °C
Index of Refraction: 1.437
Molar Refractivity: 53.66 cm3
Molar Volume: 204.4 cm3
Surface Tension: 36.2 dyne/cm
Density: 1.136 g/cm3
Flash Point: 118.3 °C
Enthalpy of Vaporization: 52.01 kJ/mol
Boiling Point: 281.3 °C at 760 mmHg
Vapour Pressure: 0.00358 mmHg at 25°C
Triethyl methanetricarboxylate Safety Profile
Safety Statements of Methanetricarboxylicacid, 1,1,1-triethyl ester (CAS NO.6279-86-3): 23-24/25
S23: Do not breathe vapour.
S24/25: Avoid contact with skin and eyes.
WGK Germany: 3
HS Code: 29171990
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