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Vinylmagnesium chloride

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Name

Vinylmagnesium chloride

EINECS 222-575-9
CAS No. 3536-96-7 Density 0.980g/mLat 20°C
PSA 0.00000 LogP 1.36870
Solubility vigorous reaction Melting Point N/A
Formula C2H3ClMg Boiling Point 66 °C
Molecular Weight 86.8038 Flash Point ?1°F
Transport Information N/A Appearance dark brown solution
Safety 16-26-36/37/39-43-45-7/8 Risk Codes 11-14/15-19-22-34
Molecular Structure Molecular Structure of 3536-96-7 (Vinylmagnesium chloride) Hazard Symbols FlammableF,CorrosiveC
Synonyms

Magnesium,chlorovinyl- (7CI,8CI);Vinylmagnesium chloride (6CI);Chloroethenylmagnesium;Ethenylmagnesium chloride;

Article Data 8

Vinylmagnesium chloride Synthetic route

75-01-4

chloroethylene

3536-96-7

vinylmagnesium chloride

Conditions
ConditionsYield
With magnesium In tetrahydrofuran
With magnesium In tetrahydrofuran at 50℃; for 0.75h;
With magnesium; ethylene dibromide In tetrahydrofuran at 25 - 60℃;
With magnesium In tert-butyl methyl ether at 50℃; for 8h; Inert atmosphere;
75-01-4

chloroethylene

7439-95-4

magnesium

3536-96-7

vinylmagnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran
Stage #1: magnesium With iodine; ethylene dibromide In tetrahydrofuran at 60 - 64℃;
Stage #2: chloroethylene In tetrahydrofuran at 60 - 64℃;
3536-96-7

vinylmagnesium chloride

100-52-7

benzaldehyde

4393-06-0

1-Phenyl-2-propen-1-ol

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 2h; Inert atmosphere;100%
In tetrahydrofuran at -10 - 20℃; Schlenk technique;95%
In tetrahydrofuran at -10℃; for 2h; Inert atmosphere;93%
6139-84-0

4-chlorobutyraldehyde

3536-96-7

vinylmagnesium chloride

167751-21-5

6-chloro-1-hexen-3-ol

Conditions
ConditionsYield
In tetrahydrofuran at -20℃; for 0.333333h;100%

(1S,2R,6R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-hydroxy-1,3-dimethyl-cyclohex-3-enecarbaldehyde

3536-96-7

vinylmagnesium chloride

(1S,5S,6R)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-6-((S)-1-hydroxy-allyl)-4,6-dimethyl-cyclohex-3-enol

Conditions
ConditionsYield
In tetrahydrofuran at 0℃;100%
457948-95-7

2-(4-fluorophenyl)-N-methoxy-N-methylacetamide

3536-96-7

vinylmagnesium chloride

A

860642-35-9

1-(4-fluorophenyl)but-3-en-2-one

B

119114-45-3

2-(4-fluorophenyl)-N-methoxyacetamide

C

C12H16FNO2

D

78191-00-1

N-Methoxy-N-methylacetamide

Conditions
ConditionsYield
Stage #1: 2-(4-fluorophenyl)-N-methoxy-N-methylacetamide; vinylmagnesium chloride In tetrahydrofuran; toluene at -30℃; for 2h;
Stage #2: With acetic anhydride In tetrahydrofuran; toluene at -30℃; for 0.5h;
Stage #3: With ammonium chloride In tetrahydrofuran; water; toluene at -30 - 10℃;
A 100%
B n/a
C n/a
D n/a
98632-84-9

(R,R)-2,3-butanediol (dichloromethyl)boronate

18680-27-8

pinanediol

3536-96-7

vinylmagnesium chloride

(s)-pinanediol {(S)-1-chloro-allyl}boronate

Conditions
ConditionsYield
With zinc(II) chloride In tetrahydrofuran; Petroleum ether to borolane (THF, -78°C) added vinylmagnesium chloride (THF), after 15 min ZnCl2 (THF) added, warmed (0°C), stirred (4h), filtered without moisture, concd. in vac., treated with petroleum ether, filtered, diol added, stirred; after 15 h aq. phase separated, extracted with ether, combined extracts dried over Na2SO4, concd., (1)H-NMR;100%
154675-56-6

bis[(μ-dimethylsilyl)(η5-cyclopentadienyl)]dichlorozirconium

3536-96-7

vinylmagnesium chloride

260786-65-0

[Zr(C5H3(CH3)4Si2C5H3)(CHCH2)2]

Conditions
ConditionsYield
In tetrahydrofuran; tetrahydrofuran-d8 dichlorozirconocene in THF and soln. of MgCl(CHCH2) in THF-d8 was sealed in vac. (-78°C); heated (5 min, -50°C); not isolated; detected by NMR;100%
1221900-15-7

C23H42O3Si

3536-96-7

vinylmagnesium chloride

1221900-35-1

C25H46O3Si

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at -40℃; for 1.5h; Inert atmosphere;100%
3536-96-7

vinylmagnesium chloride

14618-80-5

(R)-benzyl glycidol

814-68-6

acryloyl chloride

640298-47-1

Acrylic acid (R)-1-benzyloxymethyl-but-3-enyl ester

Conditions
ConditionsYield
Stage #1: vinylmagnesium chloride; (R)-benzyl glycidol With copper(l) iodide In tetrahydrofuran at 0℃; for 1h;
Stage #2: acryloyl chloride With ethylmagnesium bromide In tetrahydrofuran at 20℃; for 1.5h;
100%

Vinylmagnesium chloride Chemical Properties

IUPAC Name: Magnesium ethene chloride
Molecular Formula: C2H3ClMg
Molecular Weight: 86.80g/mol
Density: 0.975g/cm3
Boiling Point: 66 °C at 760 mmHg
Flash Point: -17 ºC
Freely Rotating Bonds: 1
The Cas Register Number of Vinylmagnesium chloride is 3536-96-7 .The chemical synonyms of Vinylmagnesium chloride (CAS No.3536-96-7) are Vinylmagnesium chloride ; Vinylmagnesium chloride solution ; Chlorovinylmagnesium ; Vinylmagnesium ; Vinylmagnesium chloride, 1.6m solution in tetrahydrofuran ; Vinylmagnesium chloride solution, ~1.7 m in tetrahydrofuran ; Vinylmagnesium chloride, 15 wt% solution in tetrahydrofuran ; Vinylmagnesiumchloride,15%(w/w)solutionintetrahydrofuran .Product categories of Vinylmagnesium chloride (CAS No.3536-96-7) are Alkenyl ; Grignard reagents ; Organometallic reagents .The molecular structure of Vinylmagnesium chloride (CAS No.3536-96-7) is.

Vinylmagnesium chloride Uses

It can be used in organic synthesis.

Vinylmagnesium chloride Safety Profile

Hazard Codes: FlammableCorrosiveC  
Risk Statements: 11-14/15-19-22-34
R11:Highly flammable. 
R19:May form explosive peroxides. 
R22:Harmful if swallowed. 
R34:Causes burns.
Safety Statements: 16-26-36/37/39-43-45-7/8-43B-30
S16: Keep away from sources of ignition. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S43: In case of fire use ... (there follows the type of fire-fighting equipment to be used.) 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S30: Never add water to this product.
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 1
F: 1-3-10

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